时间分辨光谱电化学进展

电极 /电解质的界面动力学是当代电化学基础研究的核心领域及主要的发展方向之一 .该方面研究希望能够从分子水平上对电极反应的基元步骤进行直接观察与分析 .对时间分辨光谱电化学中的红外、Raman、紫外可见等光谱技术的循呼发展现状进行了系统的介绍 ,各种光谱技术所能达到的时间分辨水平分别为 :红外 (几微秒 ) ,Raman(几十毫秒 ) ,紫外可见 (几微秒 ) .

1 BardAJ,AbrunaHD ,ChidseyCE ,etal.Theelectrode/electrolyteinterface_astatusreport.JPhysChem ,1993,97(2 8) :7147～ 71732 YeagerE .Internationalconferenceon“electronicandmolecularstructureofelectrode_electrolyteinterfaces” .JElectroanalChem ,1983,15 0 :6 79～ 6 893 林仲华 ,叶思宇 ,黄明东 ,等 .电化学中的光学方法 .北京 :科学出版社 ,19904 WhiteRE ,BockrisJO’M ,ConwayBE ,etaleds .ComprehensiveTreatiseofElectrochemistry .Vol 8,NewYork/Lon don :PlenumPress,19845 MarkJrMB ,PonsS .Aninsituspectrophotometricmethodforobservingtheinfraredspectraofspeciesattheelectrodesur faceduringelectrolysis .AnalChem ,196 6 ,38(1) :119～ 12 16 ReedAH ,YeagerE .Infra_redinternalreflexionstudiesofthegermanium/electrolyteinterface .ElectrochimActa ,1970 ,15(8) :134 5～ 135 47 FleischmannM ,HendraPJ ,McQuillanAJ.Ramanspectrafromelectrodesurfaces.JChemSoc ,ChemCommun ,1973,3:80～ 818 KunimatsuK .TheinfraredspectrumoflinearlyadsorbedCOspeciesproducedbychemisorptionofmethanolonasmoothplat inumelectrodeathighanodicpotentials .JElectroanalChem ,1983,145 :2 19～ 2 2 49 ShiC ,ZhangW ,BirkeRL ,etal.Detectionofshort_livedintermediatesinelectrochemicalreactionsusingtime_resolvedsur face_enhancedRamanspectroscopy .JPhysChem ,1990 ,94(12 ) :476 6～ 476 910 AshleyK ,PonsS .Infraredspectroelectrochemistry .ChemRev ,1988,88(4) :6 73～ 6 9511 BellSEJ .Time_resolvedresonanceRamanspectroscopy .Analyst,1996 ,12 1(11) :10 7R～ 12 0R12 GaillardF ,LevillainE .Visibletime_resolvedspectroelectrochemistry :applicationtostudyofthereductionofsulfur(S8)indimethylformamide .JElectroanalChem ,1995 ,398:77～ 8713 BewickA ,KunimatsuK ,PonsS .Infraredspectroscopyoftheelectrode_electrolyteinterphase.ElectrochimActa ,1980 ,2 5(4) :46 5～ 46 814 BewickA ,KunimatsuK .Infraredspectroscopyoftheelectrode_electrolyteinterphase .SurfSci,1980 ,10 1(1_3) :131～ 13815 LiJ ,DaschbachJ,SmithJJ ,etal.TheinfraredspectraofsurfacemetalatomvibrationsSNIFTIRSstudiesinthefarinfraredregionusingtimeresolvedFTIRtechniques .JElectroanalChem ,1986 ,2 0 9:387～ 39016 DaschbachJ,HeislerD ,PonsS .Time_resolvedinfraredspectroelectrochemistry .ApplSpectrosc ,1986 ,40 (4) :489～49117 LiJ ,DaschbachJL ,SmithJJ,etal.TheinfraredspectraofsurfacemetalatomvibrationsSNIFTIRSstudiesinthefarin fraredregionusingtimeresolvedFTIRtechniques.JElectroanalChem ,1986 ,2 0 9:387～ 39018 LiJ ,PonsS ,SmithJJ.Far_infraredspectroscopyoftheelectrode_solutioninterface .Vibrationalinteractionofadsorbedmetalatomswithsurfacestatesofagoldelectrode .Langmuir,1986 ,2 (3) :2 97～ 30 119 CheneryDH ,ChestersMA ,McCashEM .Timeresolvedfouriedtransformreflection_absorptioninfraredspectroscopy .SurfSci,1988,198:1～ 102 0 LeungLWH ,WieckowskiA ,WeaverMJ.Insituinfraredspectroscopyofwell_definiedsinglecrystalelectrodes :adsorptionandelectrooxidationofCOonPt(111) .JPhysChem ,1988,92 (2 4) :6 985～ 6 9902 1 MatsudeS ,KitamuraF ,ItoM ,etal.DynamicaspectsofmethanoloxidationonPtelectrodesbytimeresolvedinfraredreflec tionabsorptionspectroscopy .JElectroanalChem ,1989,2 74:30 5～ 3122 2 WeillerBH ,WassermanEP ,MooreCB ,etal.OrganometallicCOsubstitutionkineticsinliquidXebyfasttime_resolvedIRspectroscopy .JAmChemSoc ,1993,115 (10 ) :432 6～ 43302 3 YanigerSI,VidrineDW .DynamicFT_IRpartI :rapid_scanmethodsinspectroelectrochemistry .ApplSpectrosc ,1986 ,40(2 ) :174～ 1802 4 NakamuraM ,OgasawaraH ,ItoM ,etal.COmigrationonPt(10 0 )andPt(111)surfacesstudiedbytimeresolvedinfraredreflection_absorptionspectroscopy .SurfSci,1993,2 83(1/3) :2 48～ 2 5 42 5 HartlandGV ,QinD ,DaiHL .Fouriertransformdispersedfluorescencespectrosocpy_observationofnewvibrationallevelsinthe 5 0 0 0～ 80 0 0cm-1regionof (a)over_tilde 1A1CH2 .JChemPhys,1993,98(3) :2 46 9～ 2 4722 6 JohnsonTJ ,SimonA ,WerlJM ,etal.Applicationsoftime_resolvedstep_scanandrapid_scanFT_IRspectroscopy :dynamicsfromtensecondstotennanoseconds.ApplSpectrosc ,1993,47(9) :1376～ 138127 PalmerRA ,ChaoJL ,DittmarRM ,etal.Investigationoftime_dependentphenomenabyuseofstep_scanFT_IR .ApplSpectrosc,1993,47(9) :12 97～ 13102 8 OsawaM ,YoshiiK ,AtakaKI ,etal.Real_timemonitoringofelectrochemicaldynamic