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高温稳定TiO_2-SiO_2复合粉体的两步水热法制备 被引量:7

Preparation of TiO_2-SiO_2 Composite Powders Stabilized at High Temperature by Two-Step Hydrothermal Method
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摘要 以钛酸丁酯和硅酸乙酯为原料,通过两步水热法制备了具有高光催化活性的高温稳定TiO_2-SiO_2复合粉体.采用动态光散射粒度分析仪、差示扫描量热仪、傅里叶变换红外光谱仪、透射电子显微镜和X射线衍射仪等对TiO_2-SiO_2复合粉体进行了表征.粒度分析表明,复合粉体分散良好,颗粒大小为10~30nm,颗粒分布较窄.热分析表明,SiO_2的加入能显著提高TiO_2的热稳定性.物相分析表明:复合粉体中SiO_2含量越高,锐钛矿型TiO_2的高温稳定性越好;TiO_2/SiO_2摩尔比为1:1的复合粉体在1200℃处理2h后仍保持锐钛矿晶型.红外分析表明,800℃处理2 h前后的复合粉体中均无Ti—O—Si键.TiO_2-SiO_2复合粉体在紫外光作用下使甲基橙水溶液降解的实验表明:未经热处理的复合粉体的光催化性能和商品P25 TiO_2粉体相似;800℃和1000℃热处理2h后的复合粉体的光催化性能保持良好,远高于相同条件处理过的P25;1 200℃处理2 h后的复合粉体只有微弱的光催化活性。 TiO2-SiO2 composite powders stabilized at high temperature with high photocatalytic activity were prepared using a two-step hydrothermal method, with tetrabutyl titanate and tetraethyl orthosilicate as the materials. The powders were then characterized by means of dynamic light-scattering size analysis, DSC, FT-IR, TEM and XRD. The results of particle size analysis indicate that the composite powders disperse well in a size range of 10 - 30 nm with narrow distribution. DSC results show that the addition of silica greatly improves the high-temperature stability of titania dioxide. Phase analysis results demonstrate that the high-temperature stability of anatase titania becomes better with the increase of SiO2 content, and that the composite powders with a TiO2/SiO2 molar ratio of 1 : 1 maintain as anatase phase after being treated at 1200 ℃for 2h. FT-IR spectra show that there is no Ti-O-Si bonds in the.TiO2-SiO2 composite powders before and after the treatment at 800℃ for 2 h. Moreover, according to the degradation of aqueous methyl orange by TiO2-SiO2 composite powders under UV irradiation, it is found that ( 1 ) the photocatalysis of the composite powders without heat treatment is similar to that of commercial P25 TiO2 powders ; (2) the photocatalytic activity of the composite powders after the heat treatment at 800 and 1 000 ℃for 2 h is much higher than that of P25 ; and (3) after the heat treatment at 1200 ℃ for 2 h, the photocatalytic activity of the composite powders becomes poorer.
出处 《华南理工大学学报(自然科学版)》 EI CAS CSCD 北大核心 2009年第12期1-6,共6页 Journal of South China University of Technology(Natural Science Edition)
基金 粤港关键领域重点突破招标项目(2006Z4) 广东省科技计划项目(2006B14401001)
关键词 二氧化钛 二氧化硅 水热法 高温稳定性 光催化 titanium dioxide silica hydrothermal method high-temperature stability photocatalysis
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参考文献13

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