期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

离子液体[bmim]OH中硫醇和丙烯酸酯的快速共轭加成反应 被引量：2

A Novel Strategy for the Fast Conjugated Addition of Thiols to Acrylates using [bmim] OH as Catalyst and Solvent
下载PDF
导出
摘要 碱性离子液体[bmim]OH有效地促进硫醇和α,β-不饱和羰基化合物的迈克尔加成反应.反应在室温条件下进行,在2~15 min内可以取得良好的收益率,离子液体也可以循环回收利用. A novel protocol for the Michael addition of thiols to acrylates was developed using a basic ionic liquid [bmim] OH as catalyst and solvent.The reaction was carried out at room temperature and could obtain good yields in 2～15 min.The ionic liquid could be recovered.
作者 娄凤文 周建峰
机构地区 淮阴师范学院化学系
出处 《淮阴师范学院学报（自然科学版）》 CAS 2009年第4期322-327,共6页 Journal of Huaiyin Teachers College;Natural Science Edition
关键词 [bmim]OH 硫醇 Α Β-不饱和羰基化合物 迈克尔加成 [bmim]OH thiol acrylate conjugated addition
分类号 O629 [理学—有机化学]
  • 相关文献

参考文献17

  • 1Pachamuthu K, Schmidt R R. Synthetic routes to thiooligosaccharides and thioglycopeptides [J]. Chem Rev, 2006, 106: 160- 187.
  • 2Liu G, Huth J R, Olejniczak E T, et al. Novel p-arylthio cinnamides as antagonists of leukocyte function-associated antigen-1/intracellular adhesion molecule-1 interaction. Mechanism of inhibition and structure-based improvement of pharmaceutical properties [J]. J Med Chem, 2001, 44: 1202- 1210.
  • 3Kondo T, Mitsudo T. Etal-catalyzed carbon-sulfur bond formation, [J]. Chem Rev, 2000, 100:3205 - 3220.
  • 4Chang Y S, Wang Z D, Notter R H, et al. The synthesis of thiols selenols sulfides selenides sulfoxides selenoxides sulfones and selenones [J]. J Chem Soc Perkin Trans, 2001(1): 335 - 354.
  • 5Azizi N, Saidi M R. LiClO4 accelerated Michael addition of amines to alpha beta-unsaturated olefins under solvent-free conditions [J]. Tetrahedron, 2004, 60: 383- 387.
  • 6rendra K, Krishnaveni N S, Sridhar R, et al. Beta-cyclodextrin promoted aza-Michael addition of amines to conjugated alkenes in water[J]. Tetrahedron Lett, 2006, 47: 2125-2127.
  • 7Kumar R, Chaudhary P, Nimesh S, et al. Polyethylene glycol as a non-ionic liquid solvent for Michael addition reaction of amines to conjugated alkenes [J]. Green Chem, 2006(8) : 356- 358.
  • 8Shaikh N S, Deshpande V H, Bedekar A V. Clay catalyzed chemoselective Michael type addition of aliphatic amines to alpha, beta-ethylenic compounds [J]. Tetrahedron, 2001, 57:9045-9048.
  • 9Kamal A, Reddy D R. A simple and green procedure for the conjugate addition of thiols to conjugated alkenes employing polyethylene glycol (PEG) as an efficient recyclable medium [J]. Tetrahedron Lett, 2005, 46:7951 -7953.
  • 10Fu F, Teo Y C, Loh T P. Catalytic enantioselective Diels-Alder reaction in ionic liquid via a recyclable chiral In(Ⅲ) complex [J]. Org Lett, 2006(8): 5999-6001.

同被引文献8

引证文献2

淮阴师范学院学报（自然科学版）
2009年 第4期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部