摘要
将微晶碳和镁粉在H2气氛中反应球磨复合,球磨时间为3h,制备的镁碳复合材料的平均粒度在20~120nm,说明适量微晶碳的引入,在短时间内,可实现镁粉的纳米化。对其进行吸氢性能研究,70Mg30C材料的储氢密度,在8min内可达5.0%(wt),微晶碳含量越高,储氢时间越短。储氢体系温度瞬间升高200℃,得益于微晶碳在球磨中的助磨作用和镁粉吸氢的催化作用。
Crystallite carbon compounded used Mg with reaction ball milling in hydrogen. The average size of crystal in the composite of magnesium and carbon was 20~120nm, ball milling time for 3h, in a short time can be realization of nano-magnesium.In 70Mg30 materials, the hydrogen can be stored at 8min, 2MPa hydrogen pressure, and hydrogen stor- age density was bigger 5.0%. The crystallite carbon content was higher, stored the hydrogen time to be shorter. Stored hydrogen system temperature instantaneous to elevate 200℃, crystallite carbon was heled in the in the ball milling and the catalytic effect of magnesium powder attracted hydrogen.
出处
《化工新型材料》
CAS
CSCD
北大核心
2010年第1期70-71,98,共3页
New Chemical Materials
基金
教育部留学回国人员科研基金项目(2005-383)
关键词
镁粉
微晶碳
纳米晶
储氢密度
magnesium,crystallite carbon, nano-crystal, hydrogen-storage capacity