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氨基酸衍生物手性配体的合成

Synthesis of chiral ligands from aminophenol derivatives
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摘要 以L-酪氨酸、二羟基苯丙氨酸(多巴)、天门冬氨酸和谷氨酸为原料,经过酯化和亲核取代反应,得到系列带有氰基或烯烃基的手性氨基酸类衍生物.所有化合物的结构通过红外光谱、核磁共振氢谱、质谱和元素分析予以确认. From L-tyrosine, dihydroxyphenylalanine （DOPA）, aspartic acid, and glutamic acid, a series of chiral organic ligands aminophenol with cyanogens or ethylenes were synthesized via esterification and nueleophilie substitution reaction. The structures of these compounds were confirmed by IR, 1H NMR, MS, and elemental analysis.
作者 汪芳明 邢正 韩光范
机构地区 江苏科技大学材料科学与工程学院
出处 《江苏科技大学学报（自然科学版）》 CAS 北大核心 2009年第6期557-560,共4页 Journal of Jiangsu University of Science and Technology:Natural Science Edition
基金 江苏省高校自然科学基金资金项目(05KJB350031)
关键词 氨基酸衍生物 手性配体 合成 aminophenol derivatives chiral ligands synthesis
分类号 O621.3 [理学—有机化学]
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参考文献10

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二级参考文献49

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江苏科技大学学报（自然科学版）
2009年 第6期

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