摘要
从光诱导配合物分子内和分子间电子转移的角度,介绍了光催化制氢的研究进展,继而以Pt(Ⅱ)配合物为例,对近年来光化学能量转换中有效提高光诱导电荷分离以及含有敏化剂、电子受体和催化剂的多组分体系制氢的研究工作进行了讨论。
The progress in research of metal complexes used as efficient photosensitizer and catalyst for photocatalytic hydrogen evolution is introduced according to photoinduced intra- and intermolecular electron transfer. Furthermore, photochemical energy conversion of Pt (Ⅱ ) function complexes involving effective charge-separation and light-driven hydrogen production systems containing photosensitizer, electron relay and catalyst, is detailedly discussed.
出处
《中国材料进展》
CAS
CSCD
2010年第1期20-24,53,共6页
Materials China
基金
国家973计划资助项目(2007CB613304)
国家自然科学基金资助项目(20761006,90610034)
关键词
Pt(Ⅱ)配合物
光催化
电荷分离
制氢
platinum ( Ⅱ ) complex
photocatalysis
charge separation
hydrogen generation