钇哌啶二硫代甲酸配合物的合成及性质

Synthesis and Properties of Y(Ⅲ) Complex with Sodiumpiperidinedithiocarbaminate

在干燥的氮气氛中,使无水氯化钆与无水哌啶二硫代甲酸钠在四氢呋喃溶液中反应,合成出稀土配合物C_4H_9O[Y(SSCNC_5H_(10))_4]CH_3CN。对该配合物的红外光谱、紫外光谱、摩尔电导、热分析及在几种常见溶剂中的溶解性进行了测定。

Under dry nitrogen, the coordination complex C_4H_9O.[Y(SSCNC_5H_(10))4]·CH_3CN is prepared by reacting anhydrous YCl_3 with sodiumpiperidinedithiocar baminate(in THF). It is characterized by elemental analyses, IR and UV spectra, molar conductances, thermogravimetric and differential thermal analyses and the solubility in some general solvents.