摘要
基于稀土粉体材料Y2O3催化乙腈气体在其表面发生氧化反应而产生化学发光现象,研制了一种基于化学发光原理检测乙腈的气体传感器。研究结果表明,该传感器具有较高灵敏度和较强的选择性。在温度175℃,波长490nm条件下,其催化化学发光强度与乙腈浓度在一定范围内呈良好的线性关系,线性范围为2.9~290.0mg/m^3(r=0.9955);检出限为1mg/m^3。该传感器操作简便、性能稳定,实现了对乙腈气体的实时在线检测。
When it passed the surface of rare earth material Y2O3, acetonitrile gas was catalytically oxidized and thus yield chemiluminessence. Based on this phenomenon, a novel cataluminescence(CTL) acetonitrile gas sensor was developed in this paper. The results showed that this method had high sensitivity and good selectivity. Quantitative analysis was performed at 175℃ with detection wavelength of 490 nm. Good linearity was obtained in the range from 2.9 to 290.0 mg/m^3(r=0.9955, n=8), with the detection limit of 1 mg/m^3. This gas sensor is a simple and stable one which has been applied to the reahime and online determination of acetonitrile successfully.
出处
《分析科学学报》
CAS
CSCD
北大核心
2010年第1期21-24,共4页
Journal of Analytical Science
基金
福建省教育厅资助项目(No.JA08157)