尾式缬氨酸卟啉及其金属配合物的合成及催化性质研究

Preparation and Properties of the TailedValine Porphyrin and its Complexes

报道了５〔（对Ｎ缬氨酸丁氧基）苯基〕１０，１５，２０三（对氯苯基）卟啉（Ｈ２Ｌ）及其金属配合物ＭＬＣｌ（Ｍ＝Ｆｅ，Ｍｎ）的合成，并对其进行了元素分析、ＩＲ、ＵＶＣｉｓ及荧光光谱的结构表征．初步研究了在新的催化体系Ｏ２ＺｎＨＡｃＩｍ，ＭＬＣｌ对烯烃的催化环氧化．

A meso5〔(PNvaline butxyl)phenl〕10,15,20try(Pchloro phenyl)porphyrin(H2L)and its complexes MLCl (M=Fe,Mn)were synthsesized and strutural characterized by elemental analysis,IR,UVCis and fluroescence spectra.Epoxidation of cyclohexene was tentatively studied in the O2ZnMLClHAcIm 〔M=Fe,Mn〕.