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Effect of inorganic additives on physical and chemical properties of PEO-LiClO_4 polymer electrolyte for lithium-ion batteries

Effect of inorganic additives on physical and chemical properties of PEO-LiClO_4 polymer electrolyte for lithium-ion batteries
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摘要 Inorganic additives-added PEO-based solid composite polymer electrolyte (SCPE) was prepared using solution casting method. The effects of LiNi0.8Co0.2O2 on the physical and chemical properties of the electrolyte were investigated. The products were characterized by X-ray diffraction (XRD), Fourier transform infrared spectrometer (FTIR) and differential scanning calorimetry (DSC). The electrochemical performances of SCPE were measured. Results show that properties of the SCPE are improved significantly by adding LiNi0.8Co0.2O2 into PEO polymer electrolyte. Its conductivity reaches 5×10-4 S/cm(25 ℃) while retaining good mechanical and processing properties. Inorganic additives-added PEO-based solid composite polymer electrolyte (SCPE) was prepared using solution casting method. The effects of LiNi0. 8 Co0. 2 O2 on the physical and chemical properties of the electrolyte were investigated. The products were characterized by X-ray diffraction (XRD) , Fourier transform infrared spectrometer (FTIR) and differential scanning calorimetry (DSC). The electrochemical performances of SCPE were measured. Results show that properties of the SCPE are improved significantly by adding LiNi0.8Co0.2 O2 into PEO polymer electrolyte. Its conductivity reaches 5 × 10^-4 S/cm(25℃) while retaining good mechanical and processing properties.
机构地区 Dept. of Chemistry
出处 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2009年第6期869-872,共4页 哈尔滨工业大学学报(英文版)
基金 Sponsored by the Heilongjiang Province Post-Doctoral Foundation and Harbin Science Foundation(Grant No.2007RFXXG014)
关键词 solid composite polymer electrolyte electrochemical properties PEO LiC1Q LiNio. ~ Coo.2 02 聚合物电解质 无机添加剂 化学性质 PEO 锂离子电池 物理 傅立叶变换红外光谱仪 氯酸锂
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  • 1Fenton D E,Parker J M,Wright P V.Complexes of alkali metal ions with poly(ethylene oxide).Polymer,1973,14(11):589.
  • 2Armand M B,Chabagno J M,Duclot M,et al.Fast Ion Transport in Solid.New York:Elsevier,1979.
  • 3Scott R M,Brian G D.A novel approach for development of improved polymer electrolytes for lithium batteries.J Power Sources,2003,119-121:487-491.
  • 4Croce F,Curini R,Martineli A,et al.Physical and chemical properties of nanocomposite polymer electrolytes.J Phys Chem B,1999,103(48):10632-10638.
  • 5Zhang H,Prithwiraj M,Wunder S L.Preparation and characterization of composite electrolytes based on PEO(375)-grafted fumed silica.Solid State Ionics,2008,178(39-40):1975-1983.
  • 6Lin C W,Hung C L,Venkateswarlu M,et al.Influence of TiO_2nano-particles on the transport properties of composite polymer electrolyte for lithium-ion batteries.J Power Sources,2005,146(1-2):397-401.
  • 7Serraino F F,Croee F,Epifanio A D,et al.PEO based polymer electrolyte lithium-ion battery.J European Ceramic Soc,2004,24(6):1385-1387.
  • 8Kim S,Park S J.Preparation and ion-conducting behaviors of poly(ethylene oxide)-composite electrolytes containing lithium montmorillonite.Solid State Ionics,2007,178(13-14):973-979.
  • 9Kim S,Park S J.Preparation and electrochemical behaviors of polymeric composite electrolytes containing mesoporous silicate fillers.Electrochimica Acta,2007,52(11):3477-3484.
  • 10Wen Z,Gu Z,Itoh T,et al.An investigation of poly(ethylene oxide)/saponite-based composite electrolytes.J Power Sources,2003,119-121:427-431.

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