摘要
综述了非茂双核烯烃催化剂近十年的研究进展。重点阐述了配体上各种取代基电子效应和空间结构与催化乙烯聚合性能关系,分析了双核非茂金属烯烃催化剂催化聚合特点,指出了烯烃聚合用双核非茂催化剂发展方向。
The advances in binuclear non-metallocene catalysts for olefins polymerization in recent ten years were reviewed, especially relationship between electronic effect of the ligands, sterie bulk and their catalytic behaviors for ethylene polymerization. The trends in binuclear non-metallocene catalysts for olefins polymerization were outlined, too.
出处
《工业催化》
CAS
2010年第1期7-11,共5页
Industrial Catalysis
基金
湖北省教育厅技术创新项目(J200711001)
湖北汽车工业学院校科研基金(2008YY06)
关键词
催化化学
非茂双核烯烃催化剂
烯烃聚合
配体结构
catalytic chemistry
binuclear non-metallocene catalyst
olefin polymerization
ligand structure
