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取代双层酞菁镥(Ⅲ)光敏染料的合成与性能研究 被引量：1

Synthesis and characterization of substituted bis[doble-decker Lutetium(Ⅲ)phthalocyanine]
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摘要 设计合成了对苯甲酸-L-酪氨酸酰胺取代的双层酞菁镥(Ⅲ)光敏活性染料。"三层夹心"共轭结构具有扩大了的π电子共轭体系,有强的电荷迁移能力,扩大了光谱吸收范围,增强了光吸收强度。研究了活性染料的合成与提纯方法,并利用UV、IR、1H-NMR、13CNMR及元素分析对染料的结构进行了准确表征。 The substituted bis（doble-decker Lutetium（Ⅲ）phthalocyanine） have been synthesized.The in-plane sandwich-type complexes had a big absorbance about the sunshine for the extend the conjugation of the macro-cycle.These compounds were characterized by UV/visible,IR,^1HNMR,^13CNMR,elemental analysis and MS spectroscopes.
作者 王锦艳 刘晓云 苏桂仙 喻桂朋 蹇锡高
机构地区 大连理工大学高分子材料系
出处 《化工新型材料》 CAS CSCD 北大核心 2010年第2期69-71,共3页 New Chemical Materials
关键词 光敏染料 太阳能电池 金属酞菁 镥络合物 dye-sensitized material solar cell metallophthalocyanine lutetium complex
分类号 TQ615 [化学工程—精细化工]
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共引文献23

同被引文献22

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  • 2朱晓利,许秀枝,杨亮,林梅金,王俊东,黄金陵.两种取代酞菁锌的合成及其光物理性质的研究[J].光谱学与光谱分析,2007,27(5):953-956. 被引量：6
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化工新型材料
2010年 第2期

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