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Ni负载量对MoOx催化剂反应性能的影响

EFFECTS OF Ni LOADING ON CATALYTIC PERFORMANCE OF MoOx CATALYST
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摘要 在常压、573K下考察了Ni的负载量对MoOx催化剂性能的影响。当Ni的负载量不大于2%时,正庚烷的转化率随镍负载量的增加而增加;进一步增加镍负载量,对MoOx催化剂活性的促进作用减弱。镍的存在基本不影响正庚烷异构化选择性及其产物,但其裂解产物发生变化。 At 573K under atmospheric pressure, the effects of Ni loading on catalytic performance of MoOx catalyst were inwestigated. Adding of 0-2%Ni to MoO3, the catalytic activity of n-heptane increased with the increase of nickel content; Further increasing the nickel loading, increase of the activity became moderate. The isomerization selectivity and product of n-heptane didn't change for addition of Ni. But cracking product were affected by it.
出处 《化工中间体》 2010年第2期45-47,共3页
关键词 负载量 MoOx 正庚烷 异构化 nickel loading MoOx n-heptane isomerization
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参考文献4

  • 1T. Matsuda, H. Shiro, H. Sakagami, N. Takahashi. Isomerization of heptane on molybdenum oxides treated with hydrogen. Catal lett, 1997, 47 (2): 99-103.
  • 2T. Matsuda, Y. Hirata, S. Suga, H. Sakagami, N. Takahashi. Effect of H2 reduction on the catalytic properties of molybdenum oxide for the conversions of heptane and 2-propanol. Applied catalysis A: General, 2000, 193 (1-2): 185-193.
  • 3T. Matsuda, F. Uchijima, S. Endo, N. Takahashi. Effect of Pd loading on the catalytic properties of molybdenum oxides for the isomerization of heptane. Applied catalysis A: General, 1999, 176 (1) : 91-99.
  • 4T. Matsuda, T. Niwayama, H. Sakagami, N. Takahashi. Catalytic properties of Ni-MoO3 for the isomerization of heptane. Chem. Lett., 1997, 373-374.

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