点击化学与功能有机/聚合物材料

Click Chemistry and Functional Organic/Polymeric Materials

点击化学是以杂原子连接单元C—X—C为基础的组合化学新方法,其作为现代可持续绿色有机化学方法的典范正成为构建功能有机/聚合物材料的重要工具,受到材料科学家的广泛关注。本文介绍了点击化学的基本原理与分类,系统论述在构筑有机/聚合物光电材料、超分子聚集体与分子自组装、分子机器系统以及分子识别与传感等方面的最新进展,最后提出了傅克点击反应并展望了其发展前景。

Click chemistry is combinatorial synthesis on the basis of heteroatom linkage C--X--C. As a typical example of sustainable and green organic synthetic strategy for constructing functional organic/polymeric materials, it has aroused extensive interest among materials scientists in recent years. In this review, some basic conceptions of click chemistry and its category are introduced, and various organic/polymeric optoelectrical materials, supramolecular assemblies, molecular machine and recognition systems, as well as stimuli-responsive systems are summarized in detail. Finally, Friedel-Crafts type click chemistry and its future trend are prospected.