新型电荷转移盐的合成与表征

SYNTHESIS AND CHARACTERIZATION OFA NEW CHARGETRANSFER SALT

新型电荷转移盐的合成与表征＊＊库宗军柳士忠＊曹正太董俊萍陈晋阳（湖北大学化学系武汉４３００６１）关键词十八钼二砷酸喹啉电荷转移盐光致变色中图分类号Ｏ６２７．５２近十几年来，多金属氧酸盐用作均相和多相催化剂的报道越来越多［１］。文献报道的均相催化过程大...

 new chargetransfer salt from octadecamolybdodiarsenic acid and quinoline has been synthesized and its structure and formula are verified by using ghe technigue of IR ,TG,Uvvis,and ESR,The salt is irreversibly photochromic.and its photochromism may result from the reduction of [As2Mo18O62]6_ to heteropoly blue [As2Mo18O62]8- with simultanaus oxidation of quinoline.