摘要
dppm与CH2Cl2在Pd(OAc)2作用下反应stopped_flow动态学研究韦凤萍黄永仁(华东师范大学分析测试中心上海200061)汪汉卿(中国科学院物理研究所兰州730000关键词动态学Pd(OAc)2dppmCH2Cl2停-流中图分类号O...
The dynamic process of the reaction of CH 2Cl 2 with dppm under the action of Pd(OAc) 2was studied by stopped flow spectrofluoriphotometer.The time resolved spectra for the reaction were given at a time interval of 0.01s,and 0.2s.There were the intermediate states in the reaction process.The pseudo second order rate constant of the reaction was obtained by using Globe analysis.
出处
《化学研究与应用》
CAS
CSCD
1998年第4期392-395,共4页
Chemical Research and Application