6-羟基-2,4-二(4'-羧基苯氧基)均三嗪与Zn(Ⅱ)配合物的合成及晶体的培养

Synthesis of 2,4-Bis(4-carboxyl phenoxyl)-6-hydroxyltriazine with Zinc(Ⅱ)and Cultivation of Crystal

6-羟基-2,4-二(4'-羧基苯氧基)均三嗪与六水合硝酸锌在一定条件下可以形成配合物。文章重点介绍该配体与金属盐的摩尔比为1︰2时,用水热法培养出6-羟基-2,4-二(4'-羧基苯氧基)均三嗪和六水合硝酸锌所形成的白色粒状单晶。适宜温度为120℃,反应时间为7d。

2,4-Bis（4-carboxyl phenoxyl）-6-hydroxyltriazine and Zinc nitrate hexahydrate can form coordination complexes under the certain condition. The paper mainly introduced the white grain-shaped single crystals of coordination complex with 2,4-Bis（4-carboxyl phenoxyl）-6-hydroxyltriazine and Zinc nitrate hexahydrate can be cultivated by Hydrothermal synthesis when ligand and metallic salts were mixed together according to 1 ： 2 of mole. The appropriate temperature was 120℃.