关于A_(ai)-B_(bj)型缩聚物网络结构的研究(Ⅰ)——溶胶凝胶分配理论

The Investigation of Network Structure of A_(ai)-B_(bj) Type Polycondensate( Ⅰ)——The Sol-Gel Distribution Theory

本文考虑了分子内环化反应对溶胶凝胶分配的影响,用新的方法推导了包含各种反应参数的理论方程。以聚酯为模型化合物的实验结果支持本文所得到的理论结果。

This paper reports the effect of intramolecular cyclization reaction and proposes a new theoretical model and method, evaluates the modified sol-gel distribution theory including all parameters of reaction. Using polyesters as a model compound to test the theory, we found the theoretical values agreed with the c perimental ones.