苯酚锰(Ⅲ)四苯基卟啉配合物的合成、光谱性质和催化加氧反应

Synthesis, spectral properties and catalytic oxidation of tetraphenylporphyrinatomanganese(Ⅲ) phenolate

合成了两种新的化合物Ｃ６Ｈ５ＯＭｎ（Ⅲ）ＴＰＰ和Ｃ６Ｈ５ＯＭｎ（Ⅲ）ＴＰＰ·ＴＨＦ。测定了它们的元素组成、可见吸收光谱、红外光谱和氧化还原电位。发现它们均具有催化氧化环己烯的能力。

A new manganese porphyrin, C 6H 5OMn(Ⅲ) TPP, and its complex, C 6H 5OMn(Ⅲ)TPP·THF, have been synthesized, isolated, and characterized by IR, UV, elemental analysis and cyclic voltammetry. They can catalyze the oxidation of cyclohexene.