(2E,4E)-3-苯基-2-[2-(N-乙氧羰基甲基氨基)-苯硫基]-2,4-己二烯酸乙酯——一个新的分子内重排反应产物

Ethyl (2E,4E) 2 [2 (N Ethoxycarbonylmethylamino) phenylthio] 3 phenyl 2,4 hexadienoate ——A New Intramolecular Rearrangement Reaction Product

２，３－二氢－２－甲基－４－苯基－１，５－苯并硫氮杂卓与重氮乙酸乙酯反应，得到非预期的分子内重排的开环产物。通过元素分析、ＩＲ，１ＨＮＭＲ，ＭＳ及Ｘ－晶体衍射分析确定了它的结构，并根据产物的结构，对这一新反应的反应机理进行了探讨和研究。

From the reaction of 2,3 dihydro 2 methyl 4 phenyl 1,5 benzothiazepines with diazozcetic ester an unexpected ring open product of the intramolecular rearrangement was obtained.Its structure has been determined by elemental analysis,IR,NMR,MS and X ray diffraction and a mechanism of this new reaction was proposed.