摘要
在双原子分子核运动的波动方程中，计入分子的振转相互作用项，得出的波函数除与振动量子数有关外，还与转动量子数有关。用该波函数络程计算了高温空气中ＣＯ分子发光带系因子。计算中转动量子数Ｊ的取值为０～１８０，结果适用于低温、高温和强激波条件。
From the nuclear Schrodinger equation of a diatomic molecule with the vibration- rotation interaction term involved in, we derive the wavefunction relevant not only with vibrational quantum number, but also with rotational one, The Franck - Condon factors of the radiation band systems. ATI - X. B.- Xand B - A of CO. molecule in the high temperature air are calculated. in the paper, by use of the derived wavefunction.In the calculation, the rotational quantum number J takes values from J=0 up to J=180. The resultsfit for low or high temperature condition and the condition of strong shock-wave.
基金
云南省自然科学基金
关键词
高温空气
CO^+
分子发光带系
F-C因子
Nuclear Schrodinger equation Vibration - rotation interaction term Franck-Condon factors
