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Heavy metal concentrations in soils and plants in the vicinity of Arufu lead-zinc mine, Middle Benue Trough, Nigeria 被引量:3

Heavy metal concentrations in soils and plants in the vicinity of Arufu lead-zinc mine, Middle Benue Trough, Nigeria
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摘要 This study focused on the influence of base metal mining on heavy metal levels in soils and plants in the vicinity of Arufu lead-zinc mine, Nigeria. Soil samples (0-15 cm depth) and plant samples were collected from cul-tivated farmlands in and around the mine, the unmineralized site and a nearby forest (the control site). The samples were analyzed for heavy metals (Fe, Zn, Mn, Cu, Pb, Cr and Cd) by Atomic Absorption Spectrophotometry (AAS). The physical properties of soils (pH and LOI) were also measured. Results showed that soils from cultivated farm-lands have neutral pH values (6.5-7.5), and low organic matter contents (<10%). Levels of Zn, Pb and Cd in culti-vated soils were higher than the concentrations obtained from the control site. These heavy metals are most probably sourced from mining and agricultural activities in the study area. Heavy metal concentrations measured in plant parts decreased in the order of rice leaves>cassava tubers>peelings. In the same plant species, metal levels decreased in the order of Zn>Fe>Mn>Cu>Pb>Cr>Cd. Most heavy metals were found in plant parts at average concentrations normally observed in plants grown in uncontaminated soil, however, elevated concentrations of Pb and Cd were found in a few cassava samples close to the mine dump. A stepwise linear regression analysis identified soil metal contents, pH and LOI as some of the factors influencing soil-plant metal uptake. This study focused on the influence of base metal mining on heavy metal levels in soils and plants in the vicinity of Arufu lead-zinc mine, Nigeria. Soil samples (0-15 cm depth) and plant samples were collected from cultivated farmlands in and around the mine, the unmineralized site and a nearby forest (the control site). The samples were analyzed for heavy metals (Fe, Zn, Mn, Cu, Pb, Cr and Cd) by Atomic Absorption Spectrophotometry (AAS). The physical properties of soils (pH and LOI) were also measured. Results showed that soils from cultivated farmlands have neutral pH values (6.5-7.5), and low organic matter contents (〈10%). Levels of Zn, Pb and Cd in cultivated soils were higher than the concentrations obtained from the control site. These heavy metals are most probably sourced from mining and agricultural activities in the study area. Heavy metal concentrations measured in plant parts decreased in the order of rice leaves〉cassava tubers〉peelings. In the same plant species, metal levels decreased in the order of Zn〉Fe〉Mn〉Cu〉Pb〉Cr〉Cd. Most heavy metals were found in plant parts at average concentrations normally observed in plants grown in uncontaminated soil, however, elevated concentrations of Pb and Cd were found in a few cassava samples close to the mine dump. A stepwise linear regression analysis identified soil metal contents, pH and LOI as some of the factors influencing soil-plant metal uptake.
出处 《Chinese Journal Of Geochemistry》 EI CAS 2010年第2期167-174,共8页 中国地球化学学报
关键词 土壤重金属含量 土壤样品 植物样本 铅锌矿 尼日利亚 原子吸收光谱法 线性回归分析 amp heavy metal soil plant lead-zinc mine Benue Trough Nigeria
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同被引文献21

  • 1彭渤,吴甫成,肖美莲,谢淑容,吕焕哲,戴亚南.黑色页岩的资源功能和环境效应[J].矿物岩石地球化学通报,2005,24(2):153-158. 被引量:35
  • 2LIU X M, SONG Q J, TANG Y, et al. Human health risk assessment of heavy metals in soil-vegeta-ble sys- tem : A multi-medium analysis[ J]. Science of Total En- vironment, 2013, 463:530 - 540.
  • 3ZHENG J, CHEN K H, YAN X, et al. Heavy metals in food, house dust, and water from an e-waste recycling area in South China and the potential risk to human health [ J ]. Ecotoxicology and Environmental Safety, 2013, 96:205 - 212.
  • 4KHAN K, LU Y L, KHAN H, et al. Heavy metals in ag- ricultural soils and crops and their health risks in swat district, northern pakistan[ J]. Food and Chemical Toxieology, 2013, 58:449-458.
  • 5SORIANO A, PALLARES S, PARDO F, et al. Deposi- tion of heavy metals from particulate settleable matter in soils of an industrialised area [ J]. Journal of Geochem- ical Exploration, 2012, 113 : 36 - 44.
  • 6DIAZ D, HAHN D W, MOLINA A. Evaluation of la- ser-induced breakdown spectroscopy (LIBS) as a meas- urement technique for evaluation of total elemental con- centration in soils [ J ]. Applied Spectroscopy, 2012, 66 (1):99-106.
  • 7KHATER M A. Laser-induced breakdown spectroscopy for light elements detection in steel: State of the art [J]. Spectrochimica Acta Part B: Atomic Spectrosco- py, 2013, 81:1 -10.
  • 8JUNIOR D S, NUNES L C, CARVALHO G G A, et al. Laser-induced breakdown spectroscopy for analysis of plant materials[ J]. Spectrochimica Acta Part B : Atom- ic Spectroscopy, 2012, 71:3 - 13.
  • 9HARMON R S, RUSSO R E, HARK R R. Applications of laser-induced breakdown spectroscopy for geochemical and environmental analysis: A comprehensive review [J]. Spectrochimica Acta Part B: Atomic Spectrosco- py, 2013, 87:11 -26.
  • 10JUNIOR D S, NUNES L C, TREVIZAN L C, et al. Evaluation of laser induced breakdown spectros-copy for cadmium determination in soils [ J]. Speetrochimiea Ae- ta Part B : Atomic Spectroscopy ,2009,64 : 1073 - 1078.

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