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邛莫金矿床中的硒辉锑矿 被引量:8

Se-STIBNITE FROM QIONGMO GOLD DEPOSIT IN WESTERN QINLING, CHINA
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摘要 硒辉锑矿产于西秦岭邛莫金矿床中。与其共生的矿物有灰硒汞矿、灰硒铝矿、硒锑矿、硒块硫锑铜矿、硒镍矿、自然金以及石英、重晶石等。该矿物显微硬度VHN50=68.25~128.0kg/mm2,平均101.26kg/mm2,相当于摩氏硬度3.15、30个测点的电子探针分析结果(%):Sb57.75~66.79(平均63.25),S11.86~21.62(平均17.30),Se12.82~29.12(平均19.27),据其平均值计算的化学分子式为:Sb1.99(S2.07,Se0.93)3.00,简写式为Sb2(S,Se)3。代表性的反射率(%):(470nm)Rα’=45.33,Rγ’=31.03;(550nm)Rα’=46.75,Rγ’=33.63;(590nm)Rα’=46.06,Rγ’=:33.50;(650nm)Rα’=45.18,Rγ’=31.49。对两个Se含量仅达3%~5%的辉锑矿粉晶分析所得晶胞参数值为:a=1.1209~1,1212nm,b=1.1299~1,1303nm,c=0.3847~0,3849nm。与辉锑矿相比十分相似。 Se-stibnite was discovered in the Qiongmo gold deposit occurring in the Cambrian sili-calite and slate in the south subzone of western Qinling Mountains. Samples containing Se-stibnite were collected from the silicalite-type ores. Se-stibnite was found in quartz-barite veins in the form of dissemination or veinlet. The associated minerals include tiemannite, clasthalite, antimonselite,Se-stibioluzonite, native gold, barite and quartz. The mineral is lead-gray in colour, metallic in luster and brashy,0. 01-0. 2 mm in size, 68. 25- 128.0kg/mm2(for 50 g load ) in microhardness and Moh's = 3. 15. The reflectance values (SiC standard ) are given in 10 nm steps. The represen-tative R values are 47o0nm R'a= 45. 33, R'Y= 31. 03; 550 nm R'a= 46. 75, R'Y= 33. 63; 590nm R'a= 46. 06, R'Y= 33. 50; 650 nm R'a= 45. 18, and R'Y= 31. 49. Electron microprobe analyses of thirty points gave the results as follows (% ): Sb 57. 75% - 66. 79% (63. 25% on average ), S 11. 86% -21. 62% (17. 30% on average), and Se 12. 82% - 29. 12% (19. 27 % on average), pre-senting a formula of Sb1.99(S2.07, Se0.93)3.00 and its simplified formula is Sb2 (S, Se )3. The unit-cell parameters of Se-bearing stibnite are a = 1. 120 9- 1. 121 2 nm, b=1. 129 9 - 1. 130 3 nm,c=0. 384 7-0. 384 9 nm, which are similar to those of stibnite.
出处 《矿物学报》 CAS CSCD 北大核心 1998年第4期445-451,共7页 Acta Mineralogica Sinica
基金 国家自然科学基金 中国-奥地利国际合作项目!4880099 国家自然科学基金!49773197 中国博士后科学基金 南京大学内生金属
关键词 硒辉锑矿 金矿床 西秦岭 共生矿物 Se-stibnite gold deposit western Qinling
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