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Friedel化合物对VO_4^(3-)的吸附及其作用机制 被引量：4

Adsorption capacity of Friedel's salt for VO_4^(3-) and its mechanisms
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摘要 为了解Friedel化合物作为吸附剂去除水中VO43-的应用潜能,研究了Friedel化合物对VO34-的吸附动力学和吸附等温线,并结合吸附产物的XRD和红外光谱分析探讨了Friedel化合物的吸附作用机理.结果表明:Friedel化合物对VO34-有较高的吸附容量和吸附速率,其吸附等温线符合Langmuir等温吸附模型(R2>0.93),理论吸附容量为72.40mg.g-1.Friedel化合物对VO34-的吸附作用机理为层间离子交换和表面吸附. In order to understand the application potential of Friedel＇s salt,Ca4Al2（OH）12Cl2（H2O）4,as an adsorbent for VO4^3- removal,the adsorption behavior of Friedel＇s salt for VO4^3- from aqueous solution was examined,through investigating the adsorption kinetics and adsorption isotherms. Both the experimental and modeled data indicated that Friedel＇s salt could adsorb a large amount of VO4^3- with a high adsorption rate. The adsorption isotherm data fit the Langmuir equation well （R^20.93） and the maximum adsorption amount of VO4^3- was 72.40 mg·g^-1. The mechanisms of Friedel＇s salt adsorption of VO4^3- were interlayer ion-exchange and surface adsorption.
作者 许云峰 戴迎春 张佳 曹亚丽 刘强 吴岳英 钱光人
机构地区 上海大学环境与化学工程学院
出处 《环境科学学报》 CAS CSCD 北大核心 2010年第4期801-805,共5页 Acta Scientiae Circumstantiae
基金 国家自然科学基金项目(No. 20477024 20677037 20877053) 上海市重点学科(No. S30109) 国家重大科技专项子课题(No.2008ZX07421-002-09)~~
关键词 层状双羟基金属复合氧化物(LDH) Friedel化合物 VO4^3- 吸附 Layered Double Hydroxides （LDH） Friedel＇s salt VO4^3- adsorption
分类号 X131 [环境科学与工程—环境科学]
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参考文献17

  • 1Afshari C A, Kodama S, Bivins H M, et al. 1993. Induction of neoplastic progression in Syrian hamster embryo ceils treated with protein phosphatase inhibitors [ J ]. Cancer Research, 53 ( 8 ) : 1777-1782.
  • 2Barceloux D G. 1999. Vanadium [ J ]. Journal of Toxicology-Clinical Toxicology, 37(2) :265-278.
  • 3Birnin-Yauri U A, Glasser F P. 1998. Friedel' s salt Ca2 Al(OH) 6 (Cl, OH). 2H2 O: Its solid solution and their role in chloride binding[ J ]. Cement and Concrete Research, 28 (12) : 1713-1723.
  • 4Bothe J V, Brown P W. 2004. pHreeqC modeling of Friedel' s salt equilibria at 23 ±1℃ [J]. Cement and concrete Research, 34(6) : 1057-1063.
  • 5Brown P W, Doerr A. 2000. Chemical changes in concrete due to the ingress of aggressive species [ J ]. Cement Concrete Research, 30 (3) :411-418.
  • 6Dai Y C, Qian G R, Cao Y L, et al. Effective removal and fixation of Cr (Ⅵ) from aqueous solution with Friedel' s salt [ J ]. Journal of Hazardous Materials, 170(2-3) : 1086-1092.
  • 7Glasser F P, Kindness A, Stronach S A. 1999. Stability and solubility relationships in AFm phases-Part 1. Chloride, sulfate and hydroxide [ J ]. Cement Concrete Research, 29 (6) : 861-866.
  • 8Lazaridis N K, Jekel M, Zouboulis A I. 2003. Removal of Cr(Ⅵ), Mo (Ⅵ) and V(Ⅴ) Ions from single metal aqueous solutions by sorption or nanofiltration[J]. Separation Science and Technology, 38 (10): 2201 -2219.
  • 9Muhammad N, Parr J, Smith M D, et al. 1998. Adsorption of heavy metals in slow sand filters[ J]. Environmental Technology, 19 (6) : 633-638.
  • 10Naeem A, Westerhoff P, Mustafa S. 2007. Vanadium removal by metal ( hydr ) oxide adsorbents [ J ]. Water Research, 41 ( 7 ) : 1596-1602.

二级参考文献24

  • 1楼宗汉 徐选宇 等.矿渣水泥中钙矾石形成条件及其作用[J].硅酸盐学报,1981,9(3):295-301.
  • 2Auxilio A R, Andrews P C, Junk P C, et al. 2007. Adsorption and intercalation of Acid Blue 9 on Mg-A1 layered double hydroxides of variable metal composition [ J ]. Polyhedron, 26 (14) : 3479--3490.
  • 3Birnin-yauri U A, Glasser F P. 1998. Friedel's salt, Ca2Al(OH)6 ( Cl, OH) 2 HE O2 its solid solutions and their role in chloride binding[ J ]. Cement and Concrete Research, 28(12) : 1713-1723.
  • 4Bothe J V, Brown P W. 2004. PhreeqC modeling of Friedel's salt equilibria at 23 ± 1℃ [J]. Cement and Concrete Research, 34(6) : 1057--1063.
  • 5Das J, Sairam P B, Baliarsingh N, et al. 2007. Calcined Mg-Fe-CO3 LDH as an adsorbent for the removal of selenite [ J ]. Journal of Colloid and Interface Science, 316 ( 2 ) : 216--223.
  • 6Goh K H, Lim T T, Dong Z. 2008. Application of layered double hydroxides for removal of oxyanions: A review[ J]. Water Research, 42(6-7) : 1343--1368.
  • 7Hsu L C, Wang S L, Tzou YM, et al. 2007. The removal and recovery of Cr(VI) by Li/A1 layered double hydroxide (LDH) [J]. Journal of Hazardous Materials, 142(1-2) : 242--249.
  • 8Mandal S, Mayadevi S, 2008. Adsorption of fluoride ions by Zn-Al layered double hydroxides [ J ]. Applied Clay Science, 40 ( 1- 4) : 54--62.
  • 9Mollah M Y, Kesmez M, Cocke D L. 2004. An X-ray diffraction (XRD) and Fourier transform infrared spectroscopic (FT-IR) investigation of the long-term effect on the solidification/stabilization (S/S) of arsenic(V) in Portland cement type-V [ J]. Science of The Total Environment, 325 (1-3) : 255--262.
  • 10Park M, Choi C L, Seo Y J, et al. 2007. Reactions of Cu^2+ and Pb^2+ with Mg/Al layered double hydroxide[J]. Applied Clay Science, 37 (1-2) : 143--148.

共引文献132

同被引文献41

  • 1ZHAOHuazhang,GExiaopeng,LUANZhaokun,JIANGZhanpeng.Effects of Ca on the distribu-tion, structure and morphol-ogy of aluminum species in polyaluminum chloride[J].Chinese Science Bulletin,2004,49(12):1241-1244. 被引量：2
  • 2章兴华,周丽芸.一种生产弗雷德盐的方法:中国,201110048719.9[P].2011-03-02.
  • 3Zhang M ,Reardon E J. Removal of B,Cr,Mo ,and Se from wastewater by incorporation into hydrocalumite and ettfingite [J].Environ.Sci. Technol., 2003,37 ( 13 ) : 2947-2952.
  • 4Kirkpatrick R J.Molecular modeling of the vibrational spectra of in- terlayer and surface species of layered double hydroxides.In :The Application of Vibrational Spectroscopy to Clay Minerals and Layered Double Hydroxides [ C ]//CMS Workshop Lectures.Kloprogge J T, ed.The Clay Mineral Society, Aurora, CO., 2005,13 : 239-285.
  • 5Zhang D.Removal of arsenic from water by Friedel's salt (FS: 3CaO. A1203"CaC12" 10H20) [J] J.Hazard.Mater. ,2011,195:398-404.
  • 6Dai Y,Qian G, C ao Y, et al.Effective removal and fixation of Cr ( VI ) from aqueous solution with Friedel's salt [J ].J.Hazard.Mater., 2009, 170 : 1086-1092.
  • 7Wu Y,Chi Y, Bai H.Effective removal of selenate from aqueous solu- tions by the Friedel phase [ J ].J.Hazard.Mater., 2010,176:193-198.
  • 8Ma J, Li Z ,Zhang Y.Desilication of sodium aluminate solution by Friedel's salt (FS: 3CaO.A 1203" CaC12.10H20) [J ]. Hydrometallurgy, 2009.99,225-230.
  • 9章兴华,陆洋,刘世荣.等.一种用弗雷德盐去除水体中重金属锑的方法:中国,103265129[P].2013-08-28.
  • 10Liu Q, Li Y, Zhang J, et al,Effective removal of zinc from aqueous solution by hydrocalumite [J ].Chem. Eng.J., 2011,175 : 33-38.

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环境科学学报
2010年 第4期

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