摘要
B酸性功能化离子液体是功能化离子液体研究领域的热点,综述了当前B酸性功能化离子液体在绿色有机合成中的应用。不足之处在于:(1)B酸性功能化离子液体的酸度测定尚缺乏准确有效和简捷通用的表征方法,因而不能建立酸度与催化性能之间的定量关系;(2)研究报道的各种类型的B酸性功能化离子液体或在物化性能或在成本上不尽人意,因而设计全新结构的B酸性功能化离子液体或对报道的B酸性功能化离子液体的化学修饰仍是B酸性功能化离子液体研究中的重要内容。
Application of Brφnsted acidic ionic liquids in green organic synthesis was reviewed. Much work is to be done in this aspects due to ( 1 ) lack of accurate and general method for measurement of acidity of Brφnsted acidic ionic liquids and establishment of relationship between acidity and catalytic behaviors; (2) unsatisfactory physicochemical properties and cost of various Brφnsted acidic ionic liquids reported. Designing Brφnsted acidic ionic liquids of novel structure and chemical modification of existing Brφnsted acidic ionic liquids would be important works in this aspect.
出处
《工业催化》
CAS
2010年第2期1-6,共6页
Industrial Catalysis
基金
闽江学院科研启动项目(YKQ0805)
福建省自然科学基金项目(2008J0164)
福州市科技项目(2007-2-81)
关键词
有机合成化学
离子液体
B酸
绿色化学
有机转化
organic synthesis chemistry
ionic liquids
Brφnsted acid
green chemistry
organic synthesis