期刊文献+

改性MDI型聚氨酯文物保护材料耐光性能研究 被引量:6

Study of the light-fastness of modified MDI polyurethane for use as a relic protection material
下载PDF
导出
摘要 为了提高文物保护材料PU(一种MDI型聚氨酯)的耐光老化性能,采用紫外线吸收剂UV531、UV328和UVP对其进行改性。使用傅立叶变换红外光谱、反射光谱、光老化失重等手段表征改性材料的耐光老化性能。通过对表征结果的比较,得出了UV531改性MDI型聚氨酯比未改性MDI型聚氨酯及其它二种改性材料具有更优异的耐光老化能力,其对彩绘漆器文物样品也能起到更好的保护作用。 The UV- absorbers,UV531 ,UV328 and UVP were added into PU (an MDI polyurethane) to improve its light - fastness. FTIR,reflectance spectroscopy and light aging weight loss experiments were done to test the anti photoageing properties of the modified material. After comparative studies,it was concluded that the anti - photoageing properties of PU modified with UV531 are better than those of unmodified PU, and PU modified with UV328 and UVP. This research suggested that the modified PU with UV531 has great potential for the protection of colored lacquer relics.
出处 《文物保护与考古科学》 2010年第1期32-36,共5页 Sciences of Conservation and Archaeology
基金 陕西省教育厅专项科研计划资助(08JK460)
关键词 MDI型聚氨酯 文物保护材料 改性 耐光性能 MDI polyurethane Relic protection Modification Light - fastness
  • 相关文献

参考文献7

二级参考文献38

  • 1王芳,党高潮,王丽琴.文物保护中几种有机聚合物涂料的光降解[J].西北大学学报(自然科学版),2005,35(5):565-570. 被引量:11
  • 2[1]Schollenberger C S,Scott H,Moore R.Polyurethane VC, a Virtually Cross-Linked Elastomer[J].Rubber World,1958,137:549-555.
  • 3[2]Tarakanov O G,Nevskji L V,Beljakiv V K.[J].J Polym SciPart C.1968,23:193-199.
  • 4[3]Schollenberger C S,Stewart F D.Thermoplastic Urethane Elastomer Ultraviolet Stabilization[J].J Elastomerplastics.1972,4:294-311.
  • 5[4]Rek V. Ageing of Solid Polyester-Based Polyurethane[J].J Elastomerplastics,1984 16(3):256-264.
  • 6[5]Rej V,Bravar M,et al.Mechanical and Structural Studies of Photo-degraded Polyurethane[J].Polym.Deg.& Stab.1989,24(4):399-411.
  • 7[6]Gajewski V.Chemical Degradation of Polyurethane [J].Rubber World,1990,202(6):15-18.
  • 8[7]Rek V.Photostability of Polyurethame Elastomer Based on Two Types of Diisocyanates[J].J Elastomersplastics,1995,26(1):143-167.
  • 9[8]Hoyle C E,Kim K-J.Effect of Crystallinity and Flexibility on the Photodegradation of Polyurethanes [J].J Polym Sci.Polym Chem Ed.,1987,25(10):2631-2642.
  • 10[9]Hoyle V E,Ezzell K S,et al.Investigation of the photolysis of Polyurethanes Based on 4,4-Methylene Bis(phenyl diisocyanate)(MDI) Using Laser Flash Photolysis and Model Compounds[J].polym Degrad Stab.1989,25(2):325-343.

共引文献53

同被引文献91

引证文献6

二级引证文献20

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部