化合物[(C_(36)H_(36)N_(24)O_(12))ErNa(NO_3)Cl(H_2O)_4]·(NO_3)_2·5H_2O的合成和晶体结构

Synthesis and Crystal Structures of [(C_(36)H_(36)N_(24)O_(12))ErNa(NO_3)Cl(H_2O)_4]·(NO_3)_2·5H_2O

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摘要本文合成了化合物[(C36H36N24O12)ErNa(NO3)Cl(H2O)4]·(NO3)2·5H2O,利用X射线衍射法测定了单晶结构。晶体属正交晶系,空间群为Pna2(1),a=31.969(5),b=14.828(2),c=11.768(2),V=5578.5(2)3,Z=3,F(000)=2352,R1=0.0600,wR2=0.1719。 The title compound [（C36H36N24O12）ErNa（NO3）Cl（H2O）4]·（NO3）2·5H2O was synthesized and characterized by single-crystal X-ray diffraction. The crystal belongs to the Orthorhombie system, space group Pna2（1） with a = 31.969（5）A, b=14.828（2）A, c=11.768（2）A, V=5578.5（2）A^3, Z=3, F（000）=2352,R1= 0.0600 and wR2=0.1719 for 10541 observed reflections （I〉2σ（I））.

作者林榕光黄水望李慧林雅芬薛晓芳

机构地区福建师范大学福清分校生物与化学工程系

出处《福建师大福清分校学报》 2010年第2期26-30,共5页 Journal of Fuqing Branch of Fujian Normal University

基金福建省自然科学基金资助项目(No.2009J01018) 福建省教育厅资助项目(No.JB08252) 福建省大学生创新性实验项目

关键词瓜环自组装单晶X-射线衍射 Cucurbiturils, Self-assembly, Single crystal X-ray diffraction

分类号 O614.3 [理学—无机化学]

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化合物[(C_(36)H_(36)N_(24)O_(12))ErNa(NO_3)Cl(H_2O)_4]·(NO_3)_2·5H_2O的合成和晶体结构

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