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高固含量BA/MMA/MAA共聚乳液的合成及性能:单体配比的影响 被引量:5

Preparation and Properties of High Solid Content Copolymer Emulsion of BA/MMA/MAA: Effect of Monomer Ratio
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摘要 研究了用不同配比的单体制得的高固含量BA/MMA/MAA共聚物乳液的乳胶粒、乳液的稳定性、粘度及乳胶膜性能。发现:混合单体中MMA用量增加,乳胶粒粒径变大;聚会稳定性变差;MAA用量加大,乳液粘度变大;高固含量BA/MMA/MAA乳液聚合主要是无规聚合;共聚物聚集态为非晶态。 Particle Size, Stabilities, Viscosity and properties of films of high solid content copolymer emulsion of BA/MMA/MAA with different monomer ratio was studied. It was discovered that,with ratio of MMA getting large particle size wasgetting larger and Stabilities of polymerization was getting poorer; With ratio of MAA getting larger, Visosity was gettinglarger; high solid content emulsion of BA/MMA/MAA was mainly atactic copolymerized and was amorpous polymer.
出处 《中国胶粘剂》 CAS 1998年第6期1-3,共3页 China Adhesives
关键词 乳液聚合 BA MMA 胶粘剂 MAA 配方 单体配比 high solid content emulsion, emulsion Polymerization, monomer ratio, particle size, atactic copolymerize
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