摘要
研究了用不同配比的单体制得的高固含量BA/MMA/MAA共聚物乳液的乳胶粒、乳液的稳定性、粘度及乳胶膜性能。发现:混合单体中MMA用量增加,乳胶粒粒径变大;聚会稳定性变差;MAA用量加大,乳液粘度变大;高固含量BA/MMA/MAA乳液聚合主要是无规聚合;共聚物聚集态为非晶态。
Particle Size, Stabilities, Viscosity and properties of films of high solid content copolymer emulsion of BA/MMA/MAA with different monomer ratio was studied. It was discovered that,with ratio of MMA getting large particle size wasgetting larger and Stabilities of polymerization was getting poorer; With ratio of MAA getting larger, Visosity was gettinglarger; high solid content emulsion of BA/MMA/MAA was mainly atactic copolymerized and was amorpous polymer.
出处
《中国胶粘剂》
CAS
1998年第6期1-3,共3页
China Adhesives
关键词
乳液聚合
BA
MMA
胶粘剂
MAA
配方
单体配比
high solid content emulsion, emulsion Polymerization, monomer ratio, particle size, atactic copolymerize