期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

1,2-丙二烯型化合物的合成 被引量：2

Synthesis of 1,2-Propadienes
下载PDF
导出
摘要 1,2-丙二烯衍生物因含有累积双键在过渡金属参与的反应中显示出独具魅力的反应活性.文章以烯烃为原料,采取改进的偕二溴环丙烷脱溴-卡宾重排的方法合成系列1,2-丙二烯.该方法具有产率高、操作简便、反应条件温和、副反应少等优点.化合物(3)经IR、1HNMR、13CNMR及MS确证. 1,2-propadiene,involving cumulative double bonds,has attached much attention and shown unique reactivity in numerous protocols addressed by transition metals.The use the olefins as the starting materials,and synthetizes 1,2-propadiene via the debromonation and carbene rearrangement of gem-bisbromocyclopropane,which has the advantages of high yield,safety,easily handle and few side reaction.The compounds 3 are verified by IR、1H NMR、13C NMR and MS.
作者 吴阳锋 郑卫新 郑芬芬 严微微
机构地区 杭州师范大学材料与化学化工学院
出处 《杭州师范大学学报（自然科学版）》 CAS 2010年第2期113-117,共5页 Journal of Hangzhou Normal University(Natural Science Edition)
基金 国家自然科学基金项目(20702010 20972037) 浙江省自然科学基金项目(Y406341)
关键词 1 2-丙二烯 偕二溴环丙烷 卡宾重排 合成 1 2-propadiene gem-bisbromocyclopropane carbene rearrangement synthesis
分类号 O627 [理学—有机化学]
  • 相关文献

参考文献20

  • 1Burton B S, Pechman H V. Ueber die Einwirkung von Chlorphosphor auf Aeetondicarbonsaureather[J]. Chem Ber, 1887,20:145-149.
  • 2Schuster H F, Coppola G M. Eds. Allenes in Organic Synthesis[M]. New York: John Wiley & Sons,1984.
  • 3Patai S Ed. In The Chemistry of Ketenes, Allenes, and Related Compounds[M]. New York: John Wiley & Sons,1980.
  • 4Ma Shengming. Electrophilie addition and cyclization reactions of allenes[J]. Aec Chem Res,2009,42(10) :679-1688.
  • 5Ma Shengming. Some typical advances in the synthetic applications of allenes[J]. Chem Rev,2005,105(7):2829-2872.
  • 6Sydnes L K. Allenes from cyclopropanes and their use in organic synthesis recent developments[J]. Chem Rev,2003,103(4):1133-1150.
  • 7Ma Shengming. Transition metal-catalyzed/mediated reaction of allenes with a nucleophilic functionality connected to the a-carbon atom [J]. AceChemRes,2003,36(9):701-712.
  • 8Lu Xiyan, Zhang Chunming, Xu Zhenrong. Reactions of electron-deficient alkynes and allenes under phosphine catalysis[J]. Ace Chem Res,2001,34(7) :535-544.
  • 9Zimmer R, Dinesh C U, Nandanan E, et al. Palladium-catalyzed reactions of allenes[J]. Chem Rev,2000,100(8):3067-3126.
  • 10Taylor D R. The chemistry of allenes[J]. Chem Rev,1967,67(3) :317-359.

同被引文献25

  • 1Schuster H F, Coppola G M. Allenes in organic synthesis[M]. New York: John Wiley & Sons, 1984:1-385.
  • 2Ma Shengming. Some typical advances in the synthetic applications of allenes[J]. Chem Rev,2005,105(7):2829-2871.
  • 3Pinho e Melo T M V D. Allenes as building blocks in heterocyclic chemistry[J]. Monatsh Chern,2011,142(7) :681-697.
  • 4Kilbas B, Azizoglu A, Balci M. Incorporation of an allene unit into a-pinene via ffelimination[J]. Helv Chim Acta, 2006,89 (7) :1449-1456.
  • 5Tang Meng, Fan Chun'an, Zhang Furnin, et al. New metal-free one-pot synthesis of substituted allenes from enones[J]. Org Lett 2008,10(24) : 5585-5588.
  • 6Zhou Hongwei, I.iu Guoliang, Zeng Changying. Bismetalated carbon for tandem Wittig-type reaction via allylgallation of magnesium acetylides: A convenient and efficient method to allyl allenes[J]. J Organomet Chem, 2008,693(4) :787 791.
  • 7Kolakowski R V, Manpadi M, Zhang Yue, et al. Allene synthesis via C-C fragmentation: method and mechanistic insight[J].J Am Chem Soc,2009,131(36),12910-12911.
  • 8Ogasawara M, Ge Yonghui, Uetake K. Preparation of multisubstituted allenes from allylsilanes[J]. J Org Chem, 2005,70(10): 3871- 3876.
  • 9Brossat M, Heck M P, Mioskowski C. Bistrimethylsilylpropargylic ether: A versatile ambident synthon to access substituted allenyne ethers and a-substituted bispropargylic alcohols[J]. J Org Chem, 2007,72 ( 15 ) : 5938-5941.
  • 10Pu Xiaotao, Ready J M. Direct and stereospecific synthesis of allenes via reduction of propargylic alcohols with Cpa Zr(H)CI[J]. J Am Chem Soc,2008,130(33) : 10874-10875.

引证文献2

杭州师范大学学报（自然科学版）
2010年 第2期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部