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Gas-phase Thermolysis of 1,2,3-triazole and 1,2,3-triazine Derivatives

Gas-phase Thermolysis of 1,2,3-triazole and 1,2,3-triazine Derivatives
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摘要 Gas-phase thermolysis of 1-ethoxycarbonyl-benzotriazole under static, FVP and microwaves condition yielded N^1 and NZ-ethylbenzotriazole, 2-ethoxy-1,3-benzooxazole, biphenylene and oxazolidin-2-one. On the other hand, direct condensation and pyrolysis of naphtho[1,8-de][1,2,3]triazine with ethylisocyanate, phenylisocyanate and their isothiocayanates, benzoylisothiocyanate and thiourea at 150-160 ℃ or under microwaves irradiation produced the corresponding naphthopyrimidin-2-one derivatives.
作者 Hanan Al-Awadi Maher Riyad Ibrahim Nouria Abdel-Kareem Al-Awadi Yehia Abdou Ibrahim
机构地区 Applied Science Department Chemistry Department
出处 《Journal of Chemistry and Chemical Engineering》 2010年第4期34-40,共7页 化学与化工（英文版）
关键词 Pyrolysis HETEROCYCLES BENZOTRIAZOLES naphtho[1 8-de][l 2 3]triazine Benzooxazolones naphtho[1 8-de]pyrimid-ine-2-one naphtho[ 1 8-de] [ 1 3]oxazon-2-ones. 三嗪衍生物 气相热解 热分解 三氮唑 微波照射 苯并三唑 乙氧羰基 恶唑烷酮
分类号 TQ314.248 [化学工程—高聚物工业] TF123.72 [冶金工程—粉末冶金]
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Journal of Chemistry and Chemical Engineering
2010年 第4期

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