期刊文献+

环氧大豆油对软PVC性能影响的研究 被引量:9

Study on Influence of Epoxidized Soybean Oil on the Properties of Soft PVC
下载PDF
导出
摘要 研究了环氧大豆油对软聚氯乙烯(PVC)性能的影响。实验表明,铅盐和有机锡的热稳定性较好,单独使用硬脂酸钙、硬脂酸锌、环氧大豆油或不足量的有机锡热稳定剂时,PVC样品很快变色。环氧大豆油与硬脂酸钙、硬脂酸锌、有机锡热稳定剂并用时,环氧大豆油具有很好的协同效应;但环氧大豆油和硬脂酸钙、硬脂酸锌不能简单替代有机锡稳定剂。热重分析证明了不同热稳定剂的效果。作为辅助增塑剂,环氧大豆油用量应低于5份。 The influence of epoxidized soybean oil on the properties PVC was studied. The result was showed that lead salt and organic tin compound had better thermal stability. When zinc stearate, calcium sterate, epoxidized soybean oil or insufficient organic tin compound used separately, PVC specimens changed color quickly. The synergistic effect of epoxidized soybean oil with zinc stearate, calcium sterate or insufficient organic tin compound was obvious, but epoxidized soybean oil and zinc stearate, calcium sterate cannot substitute organic tin compound simply. The effect of different heat stabilizers was demonstrated by thermogravimetry curve. The dosage of epoxidized soybean oil, as a co-plasticizer, should not be excess five phr.
出处 《塑料助剂》 2010年第2期50-53,共4页 Plastics Additives
关键词 聚氯乙烯 热稳定性 环氧大豆油 有机锡 硬脂酸锌硬脂酸钙 增塑剂 polyvinyl chlorid heat stabilizer epoxidized soybean oil organic tin zinc stearate calcium stearate plasticizer
  • 相关文献

参考文献3

二级参考文献16

  • 1Liu Z,Erhan S Z,Calvert P D.Solid Free form Fabrication of Epoxidized Soybean Oil/epoxy Composites with Di,Tri,and Polyethylene Amine Curing Agents[J].Journal of Applied Polymer Science,2004 (93):356~363
  • 2Jue Lu,Shrikant Khot,Richard P.New Sheet Molding Compound Resins from Soybean Oil.I.Synthesis and Characterization[J].Polymer,2005 (6):71~80
  • 3Johan Samuelssona,Per-Erik Sundellb,Mats Johansson.Synthesis and Polymerization of a Radiation Curable Hyperbranched Resin Based on Epoxy Functional Fatty Acids[J].Progress in Organic Coatings,2004:193~198
  • 4Chasar W D,Hughes J M.Method of Making Oleochemical Oil Based Polyols[P].EP1432672(2004)
  • 5Adhvaryua A,Erhan S Z.Epoxidized Soybean Oil as a Potential Source of High-temperature Lubricants [J].Industrial Crops and Products,2002,15(3):247~254
  • 6Waleska Castro,David E Wellerl,Kraipat Cheenkachorn,et al.The Effect of Chemical Structure of Basefluids on Antiwear Effectiveness of Additives [J].Tribology International,2005,38(3):321~326
  • 7Benecke,P H.Elhard D J,Vijayendran R B.Plasticizers Derived From Vegetable Oil[P].EP 1 294 799.2003
  • 8Tibor Szakács,Béla Iván.Epoxidation of Thermally Degraded Poly (vinyl chloride) [J].Polymer Degradation and Stability,2004,85(3):1035~1039
  • 9Thames S F,H Yu.Cationic UV-cured Coatings of Epoxide-containing Vegetable Oils[J].Surface and Coatings Technology,1999,115(2~3):208~214
  • 10Adhvaryu A,Erhan S.Z,Perez J M.Wax Appearance Temperatures of Vegetable Oils Determined by Differential Scanning Calorimetry:Effect of Triacylglycerol Structure and its Modification [J].Thermochimica Acta,2002,395(1~2):191~200

共引文献57

同被引文献132

引证文献9

二级引证文献40

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部