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双取代聚乙炔衍生物的合成与光学性能研究 被引量：2

Study on synthesis and properties of disubstituted acetylene derivatives
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摘要 用WCl6-Ph4Sn催化下聚合生成了双取代乙炔衍生物,在产物的红外光谱上,2 205 cm-1处C-C键的伸缩振动特征吸收峰消失及1 621 cm-1处C=C双键的生成,这些特征变化证明了聚合反应的发生。单体苯丙炔酸通过肉桂酸的加成消去反应制得,单体C6H5C-CCOO(C6H4)OCOCH2CH3则通过苯丙炔酸和对羟基苯甲酸乙酯酯化制得,通过红外光谱、元素分析、XRD、紫外光谱和荧光光谱对聚合物结构和性质进行了表征,结果显示,这种共轭聚合物在光激发下能发出蓝光且聚合物能溶于普通的有机溶剂。 A disubstituted acetylene was polymerized into poly （phenylpropiolic acid-ethyl-p-hydroxybenzoate） with WCl6-Ph4Sn as catalyst and toluene as solvent. The disappearance of the characteristic vibrations at 2 205 cm^-1（ C≡C ）and the appearance of the characteristic vibrations at 1 621 cm^-l（ C=C ） indicated the polymerization of monomers. The monomer phenylpropiolic acid was obtained by addition and elimination reaction from cinnamic acid, the monomer C6H5 C≡C COO （C6H4 ）OCOCH2 CH3 was syn- thesized by esterification from phenylpropiolic acid and ethyl p-hydroxybenzoate. The structures and properties of PAs were confirmed by IR, UV, XRD. The polymer shows green light under light excitation and is soluble in common organic solvents.
作者 宫奎亮 唐建国 许申鸿 王蕊 王瑶 罗金环 刘佳 刘继宪
机构地区 青岛大学杂化材料研究所 青岛大学化学化工与环境学院
出处 《应用化工》 CAS CSCD 2010年第4期514-517,共4页 Applied Chemical Industry
基金 973前期专项(2004CCA04800) 山东省自然科学基金(Y2008B06)
关键词 双取代乙炔 荧光 聚合物 disubstituted acetylene fluorescence polymer
分类号 TQ317.5 [化学工程—高聚物工业]
  • 相关文献

参考文献9

  • 1Wang Zhang Yuan,Anjun Qin,Jacky W Y Lam,et al.Disubstituted polyacetylenes containing photopolymerizable vinyl groups and polar ester functionality:Polymer synthesis,aggregation-enhanced emission,and fluorescent pattern formation[J].Macromolecules,2007,40(9):3159-3166.
  • 2Jacky W Y Lam,Dong Yuping,Kevin K L Cheuk,et al.Helical conjugated polymers:Synthesis,stability,and chiroptical properties of poly(alkyl phenylpropiolate)s bearing stereogenic pendants[J].Macromolecules,2004,37(18):6695-6704.
  • 3Wang Zhang Yuan,Jing Zhi Sun,Dong Yongqiang,et al.Wrapping carbon nano tubes in pyrene-containing poly(phenyl acetylene) chains:Solubility,stability,light emission,and surface photovoltaic properties[J].Macromolecules,2006,39(23):8011-8020.
  • 4M Tabata,Y Sadahiro,Y Nozaki,et al.Hexagonal columns of poly(n-alkylpropiolate) produced with rhodium complex catalyst.X-ray analysis and oxygen permeability[J].Macromolecules,1996,29(20):6673-6675.
  • 5Wang Zhang Yuan,Qin Anjun,Jacky W Y Lam,et al.Functionalization of disubstituted polyacetylenes through polymer reactions:Syntheses of functional poly(1-phenyl-1-alkyne)s[J].Macromolecules,2006,39(2):467-469.
  • 6Masahiro Teraguchi,Toshio Masuda.Poly(diphenylacetylene) membranes with high gas permeability and remarkable chiral memory[J].Macromolecules,2002,35(4):1149-1151.
  • 7Jacky W Y Lam,Qin Anjun,Dong Yuping,et al.Functional disubstituted polyacetylenes:Synthesis,liquidcrystallinity,light emission,and fluorescent photopatterning of biphenyl-containing poly(1-phenyl-octyne)s with different functional bridges[J].J Phys Chem B,2006,110(43):21613-21622.
  • 8Jacky W Y Lam,Ben Zhong Tang.Functional polyacetylenes[J].Accounts of Chemical Research,2005,38(9):745-754.
  • 9徐洪耀,光善仪,张胜义,童保云,唐本忠.聚苯乙炔立体结构与光致发光性能关系的研究[J].高分子学报,2001,11(2):186-190. 被引量：4

二级参考文献10

  • 1Tang B Z，Chem Mater，2000年，12卷，1446页
  • 2Xu H，Chin J Polym Sci，1999年，17卷，391页
  • 3Xu H，J Macro Sci Pure Appl Chem，1999年，36卷，1197页
  • 4Tang B Z，Macromolecules，1999年，32卷，2569页
  • 5Xu H，高分子材料科学与工程，1999年，80卷，215页
  • 6Peng H，Chin J Polym Sci，1997年，15卷，193页
  • 7Tang B Z，Macromolecules，1997年，30卷，2209页
  • 8Tang B Z，Macromolecules，1997年，30卷，2848页
  • 9Tang B Z，Macromolecules，1997年，30卷，5620页
  • 10Bunker C E，Macromolecules，1995年，28卷，3744页

共引文献3

同被引文献9

  • 1查代军,陈义旺,谌烈,秦志勇,周丹.含空间位阻侧链取代炔烃的合成及其催化聚合[J].催化学报,2007,28(8):737-742. 被引量：5
  • 2Liu, L,Zang, Y,Hadano, S,Aoki, T,Teraguchi, M,Kaneko, T,Namikoshi, T.New achiral phenylacetylene monomers having an oligosiloxanyl group most suitable for helix-sense-selective polymerization and for obtaining good optical resolution membrane materialsMacromolecules,2010.
  • 3JiaH,Teraguchi M,AokiT,etal.Three Mechanisms of Asymmetric Polymerization of Phenylacetylenes Havinganl-Amino EtherResidueandTwoHydroxyGroupsMacromolecules,2010.
  • 4AokiT,Kokai M,Shinohara K.etal.Chiral Helical Conformation of the Polypheny lacetylene HavingO ptically-ActiveBulkySubstituentChemistry Letters,1993.
  • 5Jia H,Teraguchi M,Aoki T,et al.Three Mechanisms of Asymmetric Polymerization of Phenylacetylenes Having an l-Amino Ether Residue and Two Hydroxy Groups[J].Macromolecules,2010,43:8353-8362.
  • 6Lijia Liu,Yu Zang,Aoki T,et al.Top-Down preparation of self-supporting supramolecular polymeric membranes using highly selective photocyclic aromatization of cis-cisoid helical poly(phenylacetylene)s in the membrane state[J].Journal of the American Chemical Society,2012,(135):602-605.
  • 7Aoki T,Kaneko T,Maruyama N,et al.Helix-sense-selective polymerization of phenylacetylene having two hydroxy groups using a chiral catalytic system[J].Journal of the American Chemical Society,2003,125(21):6346-6347.
  • 8Hadano S,Kishimoto T,Hattori T,et al.Helix-sense-selective polymerization of achiral bis(hydroxymethyl)phenylacetylenes bearing alkyl groups of different lengths[J].Macromolecular Chemistry and Physics,2009,(210):717-727.
  • 9Kobatake S,Uchida K,Irie M.Single-crystalline photochromism of diarylethenes:reactivity-structure Relationship[J].ChemCommun,2002,73:2804.

引证文献2

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应用化工
2010年 第4期

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