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有机钙锌热稳定剂在硬质PVC中的热稳定性

Thermal Stability of the Organic Heat Stabilizer with Ca/Zn in Rigid PVC
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摘要 采用热失重等方法研究了有机钙锌热稳定剂在硬质PVC中的热稳定性,考察了其与不同辅助热稳定剂的协效作用。结果表明:与硬脂酸钙锌、低铅热稳定剂相比,有机钙锌热稳定剂明显延长了PVC变色的时间;β-二酮与有机钙锌热稳定剂的协效性较好;在空气和氮气2种气氛下,有机钙锌热稳定剂对PVC的热稳定性无明显变化。 Thermal stability of the organic heat stabilizer with Ca/Zn in PVC was investigated by means of thermogravimetry,and the synergistic effect of different auxiliary heat stabilizers were studied.The results showed that the organic heat stabilizer with Ca/Zn was more effective than the stabilizers with low Pb and Ca/Zn stearate for color changing time of PVC.The synergistic effect of β-diketone was the best and thermal stability of heat stabilizer in PVC with oxygen present was almost the same as that with nitrogen present.
出处 《青岛科技大学学报(自然科学版)》 CAS 2010年第2期169-172,共4页 Journal of Qingdao University of Science and Technology:Natural Science Edition
关键词 热稳定剂 聚氯乙烯 热稳定性 heat stabilizer PVC thermal stability
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  • 1Magdy W Sabaa,Riham R Mohamed,Ahmady A Yassin.Organic thermal stabilizers for rigid poly (vinyl chloride) Part IX:N-Benzoyl-N'-p-substituted phenylthiourea derivatives[J].Polym Degrad Stab,2003,81(3):431-440.
  • 2Starnes W H.Structural and mechanistic aspects of the thermal degradation of poly (vinyl chloride)[J].Prog Polym Sci,2002,27(10):2133-2170.
  • 3沈德言,胡兴洲,英新芳,齐菊英,周小蜀.聚氯乙烯树脂的不饱和度和热稳定性的关系[J].高分子学报,1997,7(2):183-187. 被引量:18
  • 4Minsker K S,Zaikov G E,Zailov V G.Achievement and research tasks for poly (vinyl chloride) ageing and stabilization[J].Macromol Symp,2005,228(1):299-313.
  • 5Sabaa M W,Oraby E H,Abdel-Naby A S,et al.Organic thermal stabilizers for rigid poly (vinyl chloride) Part XII:N-phenyl-3-substituted-5-pyrazolone derivatives[J].Polym Degrad Stab,2006,91(4):911-923.
  • 6Starnes William H Jr,Du Bin,Kim Soungkyoo,et al.Thermal stabilization and plasticization of poly (vinyl chloride) by ester thiols:update and current status[J].Thermochim Act,2006,442(22):78-80.
  • 7李海兰,马廷春,姜义文,李荣勋,刘莉,刘光烨.有机低铅稳定剂XW-1在PVC中的热稳定性[J].青岛科技大学学报(自然科学版),2008,29(4):326-329. 被引量:2
  • 8金余其,严建华,池涌,李晓东,岑可法.PVC热解动力学的研究[J].燃料化学学报,2001,29(4):381-384. 被引量:31
  • 9Nandini C.Thermal decomposition of poly (vinyl chloride)[J].Journal of Polymer Science A,Polymer Chemistry,1994,32(7):1225-1237.

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