聚乙二醇对PAMPS/PAM双网络水凝胶性能的影响

INFLUENCE OF POLY(ETHYLENE GLYCOL) ON PROPERTIES OF PAMPS/PAM DOUBLE NETWORK HYDROGELS

采用紫外光引发聚合制备了聚乙二醇(PEG)改性的聚(2-丙烯酰胺-2-甲基丙磺酸)/聚丙烯酰胺(PAMPS/PAM)双网络水凝胶.测定并比较了PEG改性前后双网络水凝胶的溶胀动力学以及单网络水凝胶中丙烯酰胺(AM)的吸收量;用扫描电子显微镜(SEM)观察了单网络水凝胶的结构;测定PEG改性前后双网络水凝胶的压缩及拉伸性能.结果表明,经PEG改性后的双网络水凝胶有较高的溶胀比;改性后单网络水凝胶更易吸收AM;改性后双网络水凝胶压缩形变率达到90%以上、拉伸形变率是未改性双网络水凝胶的2倍.

Double network （DN） hydrogels composing of poly（2-acrylamido-2-methylpropanesulfonic acid） （PAMPS） as the first network （FN） and poly（acrylamide） （PAM） as the second network （SeN）,which were prepared by ultraviolet irradiation polymerization,were modified by poly（ ethylene glycol） （ PEG）. By adding PEG into single network （SN） hydrogels,many tiny meshes have been made in the network structures; meanwhile the PAM particles of SeN are in different sizes. DN hydrogels modified by PEG become tougher and softer than those without PEG. The swelling behavior was measured gravimetrically at 28℃. The absorbed amount of acrylamide （AM） in SN hydrogels was measured by brominate titration. The structures of different SN hydrogels were successfully characterized by scanning electron microscopy （ SEM）. The compressive and tensile properties were examined by using Zwick /Roell tester. The results showed that：this PEG modified DN hydrogels exhibited higher swelling ratio than that of unmodified DN hydrogels,the former was twice times higher than the latter. Interestingly,the volume of DN hydrogels became larger with the gradual increasing amount of PEG in the hydrogels,likewise,the transmittance of DN hydrogels with various PEG amounts became lower. Modified SN hydrogels prefer to absorb AM,because the small meshes,which are in the network of hydrogels,enhance the absorbability of water and AM. Pictures of SEM demonstrate apparently that many small meshes of about 0. 05 ～ 10 μm are in the network structures and the thickness of mesh walls ranges from 0. 02 μm to 0. 2 μm. However,in the unmodified SN hydrogels no obvious meshes were found and the thickness of mesh walls is about 3 μm. Some compressive and tensile properties were enhanced,for example when the PEG = 1. 0 g,the compressive strain of modified DN hydrogels was 90% ,while that of the unmodified ones was 80%. Twice times higher tensile strain than that of unmodified DN hydrogels indicated that modified DN hydrogels had become tougher and softer.