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基于杂多酸修饰电极NO_x传感器的制备与应用 被引量:2

Application and Preparation of NO_x Sensor Based on Heteropoly Anion Film Modified Electrode
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摘要 氮氧化物NOx是一类重要的环境污染物,对其进行监测十分必要。通过电化学方法制备了金钼杂多酸薄膜修饰电极,研究了该电极的电化学行为及其对酸性水溶液中NOx的电催化作用。结果表明,在5.0×10-4—1.6×10-2mol/L范围内NOx浓度与其氧化峰电流之间呈线性关系,检出限可达8.0×10-5mol/L,满足环境水样中NOx的检测要求。 Nitrous Oxides(NOx)was a kind of important environmental pollutants, so it was necessary to monitor NOx. The Au- Mo electrode was prepared by using electrochemical methods at glassy carbon electrode. The electrechemical behavior of Au - Mo was investigated by cyclic voltammetry. The results showed that the NOx concentration and oxidation peak current was linear in the range of 5.0 ×10^-4 - 1.6×10^- 2mol/L, and the lowest- limits detected of NOx was 8.0 ×10^-5 mol/L.The modified electrode could be used for the detection of nitrous oxides(NOx) in wastewater.
作者 晏薇
出处 《资源开发与市场》 CAS CSSCI 2010年第6期490-492,516,共4页 Resource Development & Market
关键词 金钼杂多酸 化学修饰电极 NOx heteropoly acid chemically modified electrode NOx
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