摘要
以苯胺、聚硫橡胶预聚体为主要原料，采用电化学一步法原位复合，制备了聚苯胺／聚硫橡胶复合膜．用ＬＣＲ电桥、傅立叶变换红外光谱（ＦＴ－ＩＲ）、扫描电镜（ＳＥＭ）、Ｘ－射线衍射（ＸＲＤ）、Ｘ－射线能量散射谱（Ｘ－ｒａｙＥＤＳ）、热分析（ＤＳＣ、ＴＧＡ）对复合膜的导电率、结构进行了研究，讨论了它们的组成。
A series of polyaniline/thiokol rubber(PAn/TR)composite films has been prepared by electrochemical polymerization in one_step process in the solutions containing aniline and thiokol rubber prepolymer. The electric coductivity and structure of the composite films were studied by using LCR bridge,FT_IR,SEM,XRD, X-ray EDS, DSC, TGA. The relationships of the compositions,structure and properties of the composite films were discussed.
出处
《华南理工大学学报（自然科学版）》
EI
CAS
CSCD
北大核心
1999年第2期12-17,共6页
Journal of South China University of Technology(Natural Science Edition)
基金
国家自然科学基金
广东省自然科学基金
华南理工大学基金
关键词
聚苯胺
聚硫橡胶
复合膜
导电率
FT-IR
SEM
polyaniline
thiokol rubber
composite film
electric conductivity
aggregative morphology
