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天然氨基酸引发六元环碳酸酯开环聚合的研究 被引量：2

Study on Ring-Opening Polymerization of Six-membered Cyclic Carbonate Initiated by Natural Amino Acids
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摘要 研究了多种天然氨基酸存在下2,2-二甲基三亚甲基环碳酸酯(DTC)和三亚甲基环碳酸酯(TMC)的开环聚合反应。其中中性两官能团氨基酸作用下所得到聚合物的分子量和产率最高,在反应温度110°C、反应时间60h、DTC与L-苯丙氨酸摩尔比为200∶1的条件下,得到数均分子量为18900g.mol-1的聚(2,2-二甲基三亚甲基碳酸酯);在反应温度90°C、反应时间24h、TMC与L-亮氨酸摩尔比为100∶1的条件下,得到数均分子量为15000g.mol-1的聚(三亚甲基碳酸酯)。 In this paper,ring-opening polymerization of six-membered cyclic carbonate including 2,2-dimethyl trimethylene carbonate（DTC）and trimethylene carbonate（TMC）initiated by natural amino acids were investigated in detail.Results showed that polymers obtained have high yield and molar weight when polymerization carried out in the presence of neutral amino acids with two functional groups.The number-average molecular weight（Mn）of poly（2,2-dimethyl trimethylene carbonate）reaches 18 900 g·mol-1 with molar ratio of DTC to L-phenylalanine 200∶1 at 110℃ for 60 h and the Mn of poly（trimethylene carbonate）reaches 15 000 g·mol-1 with molar ratio of TMC to L-leucine 100∶1 at 90℃ for 24 h.
作者 刘继延 刘学清 张远方
机构地区 江汉大学化学与环境工程学院
出处 《化学与生物工程》 CAS 2010年第5期31-34,共4页 Chemistry & Bioengineering
基金 武汉市晨光科技基金资助项目(20065004116-39)
关键词 天然氨基酸 开环聚合 2 2-二甲基三亚甲基环碳酸酯 聚(2 2-二甲基三亚甲基碳酸酯) 三亚甲基环碳酸酯 聚(三亚甲基碳酸酯) natural amino acid ring-opening polymerization 2,2-dimethyl trimethylene carbonate poly （2,2-dimethyl trimethylene carbonate） trimethylene carbonate poly（trimethylene carbonate）
分类号 TQ316.3 [化学工程—高聚物工业]
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参考文献9

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同被引文献16

  • 1刘盛辉,郎美东.新一代生物医用材料[J].高分子通报,2005(6):113-117. 被引量：10
  • 2黄霞,郑元锁,高积强,陈家昌.一种新的可生物降解聚碳酸酯的合成与表征[J].合成树脂及塑料,2007,24(4):36-39. 被引量：3
  • 3Carpentier J F, Helou M. Poly ( trimethylene carbonate) from biometals - based initiators/ catalysts: highly efficient immortal ring- opening polymerization processes [J]. Advances Synthesis and Catalysis, 2009,351 : 1312 - 1324.
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  • 6Seow W Y, Yang Y Y. Functional polycarbonates and their self - assemblies as promising non - viral vectors[J]. Journal of Controlled Release, 2009, 139: 40-47.
  • 7Zhang C, Liao L Q, Gong S. Recent developments in microwave - assisted polymerization with a locus on ring-opening polymerization [J]. Green Chemistry, 2007, 9:303-314.
  • 8Lee J, Cho E C, Cho K. Incorporation and release behavior of hydrophobic drug in Functionalized poly (D, L - laetide)- block - poly (ethylene oxide) mieelles[J]. Journal of Controlled Release, 2004, 94(23): 323 - 335.
  • 9Shu Y Y, Xing G F, Li B C. Biodegradability of CO2 copolymers synthesized by using macromolecule - bimetal catalysts [J]. Polymers for Advanced Technologies. 1996,7:605 - 608.
  • 10Chen H, Yan G P, Li L, et al. Synthesis, characterization and properties of ε - caprolactone and carbonate copolymers [J]. Journal of Applied Polymer Science, 2009,114(5) : 3087 - 3096.

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化学与生物工程
2010年 第5期

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