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有机化合物的氧化溴化研究进展 被引量：6

Recent Progress in Oxidative Bromination of Organic Compounds
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摘要 综述了几类在氧化剂存在下的羰基α位、芳环、烯烃双键、烷基苯苄位及烷烃上的氧化溴化反应。氧化溴化体系主要有Br-/H2O2和Br-/BrO3-体系。总结了不同反应条件对反应收率的影响,并展望了该领域的研究前景。 The research progress on oxidative bromination reactions of compounds with functional groups including α-carbonyl hydrogen,the ring of arene,alkene double bond,the side chain of arene and alkanes is reviewed.The main oxidation of bromide system is Br^-/H2O2 and Br^-/BrO3^-.The different conditions of reaction are discussed in detail.The perspective on this research field is also suggested.
作者 居洁 高建荣 李郁锦
机构地区 浙江工业大学化学工程与材料学院
出处 《应用化学》 CAS CSCD 北大核心 2010年第6期621-625,共5页 Chinese Journal of Applied Chemistry
基金 浙江省自然科学基金(Y407306)资助项目
关键词 氧化溴化 过氧化氢 芳烃 oxidative bromination hydrogen peroxide arene
分类号 O621.3 [理学—有机化学]
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参考文献35

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同被引文献45

  • 1姜辉,赵素娟,赵巍,王海波,王海洋,王守凯.5-溴代胡椒环的合成方法研究[J].精细化工中间体,2012,42(3):47-49. 被引量：3
  • 2Barhate N B, Gajare A S,Wakharkar R D,et al. Simple and Efficient Chlorination and Bromination of Aromatic Compounds with Aqueous TBHP( or H2 02 ) and a Hydrohalic Acid [ J ]. Tetrahedron Lett, 1998,39 (36) :6349-6350.
  • 3Mallick S, Parida K M. Studies on Heteropoly Acid Supported Zirconia: Ⅱ. Liquid Phase Bromination of Phenol and Various Organic Substrates [ J ]. Catal Commun,2007,8 (6) : 889-893.
  • 4Wong Shetin, Hwang Chichau, Mou Chungyuan. Tungstated Zirconia Catalyzed Bromination of Phenol Red Under Nearly Neutral Solution[J]. Appl Catal B,2006,63( 1 ) :1-8.
  • 5Parida K M, Parija S, Das J, et al. Preparation, Characterisation of Molybdophosphoric and Tungstophosphoric Acid Intercalated Zinc Aluminium Iqydrotalcite-like Compounds and Their Catalytic Evaluation Towards the Oxidative Bromination of Phenol[ J]. Catal Commun,2006,7( 11 ) :913-919.
  • 6Das D P, Parida K M. Liquid Phase Bromination of Phenol: HI. Over Heteropoly Acid (HPA)-impregnated Titanium Phosphate(TiP) [ J ]. J Mol Catal A : Chem ,2006,253 (1) :70-78.
  • 7Das D P, Parida K M. Liquid Phase Bromination of Phenol: Ⅱ. Over Heteropoly Acid (HPA)-impregnated Zirconium Phosphate(ZrP) [J]. Appl Catal A,2006,305( 1 ) :32-38.
  • 8Mallik S, Parida K M, Dash S S. Studies on Heteropoly Acid Supported Zirconia: Ⅲ. Oxidative Bromination of Phenol Using Phosphotungstie Acid Supported on Zirconia [ J ]. J Mol Catal A : Chem ,2007 ,261 ( 1 ) : 172-179.
  • 9Das D P, Parida K M. Liquid Phase Bromination of Phenol over Titania Pillared Zirconium Phosphate and Titanium Phosphate[ J]. Catal Commun,2006,7( 1 ) :68-72.
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引证文献6

二级引证文献11

应用化学
2010年 第6期

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