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固体酸CsH_2PO_4的制备方法研究

The Study of the CsH_2PO_4 Solid Acid's Preparation Methods
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摘要 主要研究了几种不同制取方法和不同因素对固体酸CsH2PO4的影响,并用X-射线衍射仪(日本理学)分析表征其结构,得出制备酸CsH2PO4的最佳条件和方法是:选择在70℃恒温,Cs+浓度为15.4mol.L-1,pH=7的反应条件下甲醇萃取。 The effcet of different preparation methods and different reaction conditions on crystal form of polycrystalline power CsH2PO4 are studied.The crystal structure are analyed by X-ray diffraction(Rigaku,JAPAN).The best condition is as follows:70℃ isothermal reaction,the concentration of Cs+ is 15.4mol·L-1,acidity control pH=7 and methanol is selected as extraction agent.
出处 《安阳师范学院学报》 2010年第2期72-76,共5页 Journal of Anyang Normal University
关键词 CsH2PO4 晶型 制备 固体酸 Crystal form Preparation Solid acid
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参考文献13

  • 1葛磊,冉然,蔡锐,邵宗平.固体酸燃料电池[J].化学进展,2008,20(2):405-412. 被引量:4
  • 2Fitigerald R.Solid acids show potential for fuel cell electrolytes[J].Physics Today,2001,(7):22-24.
  • 3Haile S M,Boysen D A,Chisholm C R I,et al..Solid acids as fuel cell electrolytes[J].Nature,2001,(410):910-912.
  • 4Boysen D A,Uda T,Chisholm C R I,et al..High performance sohd acidfuel cells through humidity stabilization[J].Science,2004,(303):68-70.
  • 5Uda T,Boysen D A,Chisholm C R I,et al..Alcohol fuel cells at optimal temperatures[J].Electrochemical and solid-State Letters,2006,(9):261-264.
  • 6Uda T,Halle S M.Thin-membrane solid-acid fuel cell[J].Electrochemical and Solid-State Letters,2005,(8):245-246.
  • 7Otomo J,Tamnki T,Nishida S,et al..Effect of water va-por Oil proton conduction of cesium dihydrogen phosphateand application to intermediate temperature fuel cells[J].Journal of Applied Electrochemistry,2005,(35):865-870.
  • 8Halle S M,Cslkin8 P M.X-Ray Diffraction Study ofCs5(HS04),(H2PO,)2,a New Solid Acid with a UniqueHydrogen-Bond Network[J].Solid State Chem,1998,(140):251-265.
  • 9Haile S M,Calkim P M,Boysen D A.Superprotonic con·ductivity in B-Cs,(HS04)2(Hx(P,S)04)2[J].SolidState lonics,1997,(97):145一151.
  • 10Takeya S,Hayashi S,Fujihisa H,et al..Phase transition in a superprotonic conductor Cs2(HSO4)(H2PO4) induced by water vapor[J].Solid State lonics,2006,(177):1275-1279.

二级参考文献59

  • 1王诚,毛宗强,陈荣华,王革华,谢晓峰.小型燃料电池的研究现状与应用前景分析[J].化学进展,2006,18(1):30-35. 被引量:15
  • 2衣宝廉(Yi B L).燃料电池-高效、环境友好的发电方式( Fuel Cell: Hish Efficient, Environmentally Friendly of GenemlJng Electricity ).北京:化学工业出版社(Beijing:Chemical Industry Press),2000.1-4
  • 3衣宝廉(Yi B L).燃料电池-原理·技术·应用(Fuel Eell: Principle, Technology and Applications).北京:化学工业出版社(Beijing:Chemical Industr yPress),2004.7-8
  • 4黄镇江(Huang Z J).燃料电池及其应用(Fuel Cell and Its Applications).北京:电子工业出版社(Beijing:Publishing House of Electronic Industry),2005.6-13
  • 5Hogarth W H J, da Costa J C D, Lu G Q. J. Power Sources, 2005, 142:223-237
  • 6Haile S M, Boysen D A, Chisholm C R I, et al. Nature, 2001, 410:910-912
  • 7Boysen D A, Uda T, Chisholm C R I, et al. Science, 2004, 303:68-70
  • 8Uda T, Boysen D A, Chisholm C R I, et al. Electrochemical and Solid-State Letters, 2006, 9:261-264
  • 9Uda T, Halle S M. Electrochemical and Solid-State Letters, 2005, 8:245-246
  • 10Matsuo Y, Saito K, Kawashima H, et el. Solid State Commun., 2004, 130:411-414

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