摘要
合成了铜(Ⅱ)与3-羧基水杨醛和邻菲咯啉的配合物[Cu(sal)(phen)].4 H2O(sal为3-羧基水杨醛负二价离子,phen为邻菲咯啉),采用单晶X射线衍射法测定了配合物的晶体结构.结果表明,合成的晶体属于三斜晶系p墿空间群;晶体参数a=0.673 02(10)nm,b=1.102 11(19)nm,c=1.488 3(2)nm,α=109.275(2)°,β=91.991(2)°,γ=103.514(2)°;分子中Cu(Ⅱ)离子处于平面四方场配位环境中.
A copper（Ⅱ） ternary complex [Cu（sal）（phen）]·4H2O was synthesized（sal is the dianion of 3-carboxylsalicylaldehyde,and phen is 1,10-phenanthroline）.The crystal structure of the synthesized complex was determined by means of single crystal X-ray diffraction.Results indicate that the synthetic crystal belongs to triclinic system with space group pī.The unit cell parameters are a = 0.673 02（10） nm,b = 1.102 11（19） nm,c = 1.488 3（2） nm,α = 109.275（2）°,β = 91.991（2）°,and γ = 103.514（2）°.Besides,Cu（Ⅱ） in the crystal is four coordinated in a square-plane field.
出处
《化学研究》
CAS
2010年第3期11-14,共4页
Chemical Research
关键词
3-羧基水杨醛
邻菲咯啉
铜配合物
合成
晶体结构
3-carboxylsalicylaldehyde
1
10-phenanthroline
copper complex
synthesis
crystal structure
