2,2′-(1,2-亚乙基双氮次甲基)二喹啉及其Cu^(2+)、Zn^(2+)、Ni^(2+)、Mn^(2+)配合物的合成与表征

SYNTHESIS AND CHARACTERIZATION OF COMPLEXES OF Cu(Ⅱ), Zn(Ⅱ), Ni(Ⅱ) AND Mn(Ⅱ) WITH SCHIFF BASES LIGAND 2,2′ (1,2 ETHYLENEBISNITRILOMETHYLIDYNE) DIQUINOLINE

本文报道２，２′－（１，２－亚乙基双氮次甲基）二喹啉及其与Ｃｕ２＋、Ｚｎ２＋、Ｎｉ２＋、Ｍｎ２＋配合物的合成，并通过元素分析、红外光谱、紫外光谱、Ｘ－射线粉末衍射、热分析及核磁共振等手段对配体和配合物进行了表征。配合物的化学组成为Ｍ．Ｌ．（ＣｌＯ４）２·Ｈ２Ｏ（Ｍ＝Ｃｕ２＋、Ｚｎ２＋、Ｎｉ２＋、Ｍｎ２＋离子；Ｌ＝Ｃ２２Ｈ１８Ｎ４）。

The title complexes M·L·(ClO 4) 2·H 2O (M=Cu 2+ , Zn 2+ , Ni 2+ , Mn 2+ ; L=C 22 H 18 N 4) were synthesized by the Schiff bases ligand derived from quinoline 2 formaldehyde and ethylene diamine The new compounds were characterized by elementary analysis, IR, UV, 1H NMR spectra X ray powder diffraction and thermoanalysis