摘要
对双膦配体羰基铁（Ⅱ）化合物的紫外－可见光谱主要吸收峰作出了归属，讨论了确定金属有机化合物ＵＶ－ＶＩＳ、Ｍ－ＬＣＴ带的方法，研究了卤素对Ｍ－ＬＣＴ带、ｄ－ｄ＊跃迁吸收的影响以及ＣＴ带的浓度效应。
The main absorption peaks of UV Vis spectra were assigned for Iron(II) diphosphine carbonyl compounds. The distinguishing M LCT band's methods of UV Vis spectra for organometallic compounds have been discussed. Also the effect of halogen on M LCT bands,d-d * transient bands and concentration effect for M LCT bands were studied.
出处
《分析科学学报》
CAS
CSCD
1999年第1期6-9,共4页
Journal of Analytical Science
基金
国家自然科学基金
关键词
有机铁
双膦配体
羰基铁
光谱
UV Vis spectra, Photochemical sequence, M LCT bands, Concentration effect
