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NO供体亚硝酸异戊酯作用下汉斯酯的芳香化反应研究 被引量:1

The aromatization of Hantzsch dihydropyridines with NO donor isoamyl nitrite
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摘要 4-Sustituted derivatives of Hantzsch 1,4-dihydropyridine were oxidized by nitric oxide donor isoamyl nitrite in CH3CN at room temperature to give the corresponding pyridine derivatives.When 4-substituted group was methyl,ethyl,phenyl respectively,4-nitrophenyl or 4-methoxyphenyl respectirely,it was preserved.But when the group was 2-furyl or 2-phenylethenyl,products partly removing substituent were produced. 4-Sustituted derivatives of Hantzsch 1,4-dihydropyridine were oxidized by nitric oxide donor isoamyl nitrite in CH3CN at room temperature to give the corresponding pyridine derivatives.When 4-substituted group was methyl,ethyl,phenyl respectively,4-nitrophenyl or 4-methoxyphenyl respectirely,it was preserved.But when the group was 2-furyl or 2-phenylethenyl,products partly removing substituent were produced.
出处 《化学研究与应用》 CAS CSCD 北大核心 2010年第6期767-769,共3页 Chemical Research and Application
基金 教育部创新团队经费支持
关键词 亚硝酸异戊酯 汉斯酯 芳香化 NO供体 isoamyl nitrite hantzsch aromatization nitric oxide donor
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  • 1K. J. Lee,D. J. Kuchynka,J. K. Kochi,Inorg. Chemtracts . 1990
  • 2R. D. Bach,T. H. Taaffee,S. J. Rajan,J. Org. Chemtracts . 1980
  • 3M. Wiessler,Angew. Chemtracts . 1974

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