反向原子转移自由基反应体系及其研究进展

Reaction System and Research Progress of Reverse Atom Transfer Radical

反向原子转移自由基聚合(R-ATRP)是一种更优于传统ATRP方法的活性/可控聚合方法。本文概述了反向ATRP的反应机理,详细介绍了其反应体系的研究进展,包含聚合方法、引发剂、催化剂、单体等方面,并对反向原子转移自由基聚合研究的发展方向进行了展望。

Reverse atom transfer radical polymerization（RATRP） was a new living/controlled poly merization,better than atom transfer radical polymerization（ATRP）.The mechanism of RATRP was summarized,the research progress of reaction system in terms of polymeriz ation,nitiators,catalytic systems and monomers were introduced.Finally,some helpful advices for future study on reverse atom transfer radical polymerization（RATRP） were proposed.