摘要
采用水热法合成了新的配合物[Ni(H2O)6].[Ni2(phen)2(BTC)2(H2O)4].4H2O(phen=邻菲啰啉;BTC=均苯三甲酸),采用X射线单晶衍射结构分析及元素分析、红外光谱等表征,并用TGA检测了该配合物的热稳定性.晶体属于三斜晶系,空间群为P-1,晶胞参数a=0.84038(7)nm,b=0.92048(8)nm,c=1.64793(14)nm,α=97.3850(10)°,β=102.7930(10)°,γ=104.9700(10)°,V=1.17736(17)nm3,F(000)=622,Z=1.标题化合物的不对称结构是由NiO6单元和1个二聚物Ni2N4O12单元组成的,该二聚物单元通过2个邻菲啰啉和2个均苯三甲酸分子构筑了1个八元环.氢键将2个独立的结构单元连接成三维结构.
The complex [Ni（H2O）6]·[Ni2（phen）2（BTC）2（H2O）4]·4H2O（H3BTC benzene-1,3,5-tricarboxylic acid,phen =1,10-phenanthroline）was synthesized from the hydrothermal reaction and characterized by single crystal X-ray diffraction analysis,element analysis and infrared spectrum.The result shows that the crystal structure belongs to Triclinic system,space grou P-1 with a=0.840 38（7）nm,b= 0.920 48（8）nm,c=1.647 93（14）nm,α=97.385 0（10）°,β=102.793 0（10）°,γ=104.970 0（10）°,V=1.177 36（17）nm3,F（000）=622,Z=1.The asymmetrical structure of the polymer consists of NiO6 unit and a dimeric Ni2N4O12unit,and a eight-membered ring is constructed through two phen and two BTC ligands.The two isolated structure are linked further by hydrogen bonds（O—H···O）to form three dimensional supremolecular structure.
出处
《分子科学学报》
CAS
CSCD
北大核心
2010年第3期163-167,共5页
Journal of Molecular Science
基金
国家自然科学基金资助项目(20731002)
关键词
水热合成
氢键
三维结构
hydrothermal synthesis
hydrogen bond
three dimensional structure
