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裂解炉管内自由基反应模型的研究进展 被引量：8

PROGRESS OF STUDY ON FREE-RADICAL MECHANISM MODEL IN CRACKING FURNACE TUBE
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摘要 从石油烃热裂解自由基反应网络构建、反应动力学参数估算以及动力学模型建立3个方面综述了裂解炉管内自由基反应模型的研究进展,并展望了该模型的发展对石油烃原料组分测定提出的新要求。 In this paper,the progress of study on free-radical mechanism model in cracking furnace tubes was reviewed through the generation of free-radical mechanism reaction networks,the calculation of reaction thermodynamics parameters,and the construction of dynamic model in tubes.As well,increased requirements of analysis of the components in petroleum hydrocarbon feeds from the development of this model were proposed.
作者 李蔚 张兆斌 周丛 张永刚 王国清
机构地区 中国石油化工股份有限公司北京化工研究院
出处 《乙烯工业》 CAS 2010年第2期1-6,共6页 Ethylene Industry
关键词 自由基机理模型 反应动力学 裂解反应 热裂解 Free-radical mechanism model,Reaction dynamics,Pyrolysis reaction,Thermo pyrolysis
分类号 TQ203 [化学工程—有机化工]
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参考文献16

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二级参考文献38

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共引文献35

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二级引证文献12

乙烯工业
2010年 第2期

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