期刊文献+

稀土离子掺杂TiO_2-20wt%SnO_2薄膜湿敏性能研究

A STUDY ON THE HYMIDITY SENSING PROPERTIES OF RE-DOPED TiO_2-20wt%SnO_2 FILMS
下载PDF
导出
摘要 本试验采用溶胶-凝胶工艺在印有电极的石英玻璃表面,通过浸渍-提拉法制备稀土离子掺杂的TiO2-20wt%SnO2复合薄膜.研究当测试频率为0.01kHz时,烧结温度和稀土掺杂量对薄膜湿敏性能的影响.试验结果表明:在400℃和500℃下烧结的薄膜的湿敏性能要优于在600℃和700℃烧结的薄膜的湿敏性能;掺杂稀土离子的薄膜的感湿性能得到了改善,固有阻值降低;400℃烧结的0.5wt%La2O3掺杂的薄膜在45~95RH%湿度范围内阻抗值下降两个数量级;500℃下烧结的0.2wt%CeO2掺杂的薄膜在25~95RH%湿度范围内阻抗值下降两个数量级. In this paper,the use of sol-gel method for preparing RE-doping TiO-2-20wt%SnO-2 films on quartz glass plates is introduced. The films' surface is pre-printed with comb-like Ag electrode by way of dip-coating. The effects of sintering temperature and RE-doping on humidity sensing properties of films are studied at the measuring frequency of 0. 01 kHz. Experimental results show that the assemblies which are sintered at 400℃ and 500℃ appear better humidity sensitivity than those sintered at 600℃ and 700℃. The humidity sensitivity is improved through RE-doping and the intrinsic impedance is decreased. The impedance of 0. 5wt% of La2O3 doped film sintered at 400 ℃ decreases by two orders of magnitude in the humidity range of 45-95 RH% ,while the impedance of 0. 2wt% of CeO2 doped film sintered at 500 ℃ decreases by two orders of magnitude in the humidity range of 25-95 RH%.
出处 《内蒙古工业大学学报(自然科学版)》 2010年第2期93-99,共7页 Journal of Inner Mongolia University of Technology:Natural Science Edition
基金 国家自然科学基金项目资助(50562003)
关键词 二氧化钛 薄膜 稀土 湿敏性能 离子掺杂 TiO- 2 film rare earth humidity sensing ion doping
  • 相关文献

参考文献14

  • 1应皆荣,姜长印,万春荣,何培炯.TiO_2基陶瓷湿敏元件的研究和发展[J].功能材料,2000,31(6):565-568. 被引量:4
  • 2Chaudhary V A ,Mulla I S,Vijayamohanan K. Selective Hydrogen Sensing Properties of Surface Functionalized Tin Oxide[J]. Sensors and Actuators B:Chemical. 1999,223(55):154-160.
  • 3Dieguez A, Romano-Rodriguez A, Morante J R,et al. Morphological Analysis of Nanocrystalline SnOz for Gas Sensor Applications [J]. Sensors and Actuators B. 1996,31(1-2): 1-8.
  • 4Racheva T M ,Critchlow G W. SnO2 Thin Films Prepared by Sol-gel Process [J].Thin Solid Films. 1997,292:299 -302.
  • 5Tai W P,Oh J H. Fabrication and Humidity Sensing Properties of Nanostructured TiO2-SnO2 Thin Films [J].Sensors and Actuators B. 2002,85 : 154- 157.
  • 6Tai W P,Oh J H. Preparation and Humidity Sensing Behaviors of Nanocrystalline SnOz/TiOz Bilayered Films [J]. Thin Solid Films. 2002,422 : 220- 224.
  • 7Shi Z M, Yu W G, Bayar Xin. Study of Crystallization Behavior of Ce^4+-modified Titania Gels [J]. Scripta Materialia. 2004,50:885-889.
  • 8Shimizu Y,Okada H,Arai H. Application of La2O3-TiO2 Porous Glass-ceramic System to a Humidity Sensor [J]. Journal of the Ceramic Society of Japan. 1987,95 : 726- 729.
  • 9Stambolova I,Konstantinov K,Vassilev S,et al. Lanthanum Doped SnO2and ZnO Thin Films Sensitive to Ethanol and Humidity [J]. Materials Chemistry and Physics. 2003,63:104-108.
  • 10Sotter E,Vilanova X,Llobet E,et al. Thick Film Titania Sensors for Detecting Traces of Oxygen[J]. Sensors and Actuators B. 2007,127: 567.

二级参考文献11

共引文献3

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部