摘要
利用自行搭建的数字激光全息干涉法测量流体液液、气液质扩散系数的实验装置,在标准大气压下,温度在278.15—338.15 K内,测量了含氧替代燃料碳酸二乙酯分别在正庚烷和空气中21个温度点的质扩散系数;同时,使用Wilke-chang方程、Scheibel方程和Reddy-Doraiswamy方程对碳酸二乙酯在正庚烷中的质扩散系数进行了估算,并与实验数据进行了比较分析。为替代燃料碳酸二乙酯的科研开发提供了热物性基础数据。
The digital image holograph interferometry technique was used to measure the mass diffusion coefficient of liquid-liquid and gas-liquid fluids with self-built experimental set-up.The mass diffusion coefficients of diethyl carbonate were separately measured in heptane and in air at 21 different temperatures from 278.15 to 338.15 K under atmospheric pressure.The mass diffusion coefficients of diethyl carbonate in heptane were estimated by using Wilke-chang equation,Scheibel equation and Reddy-Doraiswamy equation,and the experimental results were compared with the values calculated by the equation.The study provides the basic thermophysical properties for the development of diethyl carbonate as fuel substitute.
出处
《化学工程》
CAS
CSCD
北大核心
2010年第6期57-60,共4页
Chemical Engineering(China)
基金
国家自然科学基金资助项目(50676069
50836004)
关键词
激光全息干涉
质扩散系数
碳酸二乙酯
正庚烷
空气
digital image holograph interferometry
mass diffusion coefficient
diethyl carbonate
heptane
air