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水性聚氨酯胶膜的耐水性能研究 被引量：4

Study on the water-resistance of waterborne polyurethane film
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摘要 采用预聚体法,以聚酯多元醇、甲苯二异氰酸酯、二羟甲基丙酸(DMPA)制备了聚酯型水性聚氨酯乳液,考察了亲水扩链剂DMPA用量、NCO/OH值、中和剂的种类、中和度、扩链剂乙二胺用量对乳液涂膜耐水性的影响,制备了耐水性较好的水性聚氨酯乳液。 The polyester waterborne polyurethane dispersions were prepared with polyester polyol,toluene-2,4-dissocyanate（TDI） and 2,2-dimethylolpropionic acid（DMPA）.The influence of the amount of hydrophilic chain extending agent DMPA,the ratio of NCO/OH,the species of neutralizer,neutralization degree,crosslinking agent ethylene diamine were investigated.The water resistance of cast film was improved.
作者 陈建福 施伟梅
机构地区 漳州职业技术学院食品与生物工程系 赣南医学院药学院
出处 《胶体与聚合物》 2010年第2期62-65,共4页 Chinese Journal of Colloid & Polymer
关键词 水性聚氨酯 胶膜 耐水性 Waterborne polyurethane Film Water-resistance
分类号 TQ323.8 [化学工程—合成树脂塑料工业]
  • 相关文献

参考文献7

  • 1Bao L H, Lan Y J, Zhang S F. Synthesis and properties of waterborne polyurethane dispersions with ions in the soft segments[J]. J Polym Res,2006,13:507-514.
  • 2Narayan R, Chattopadhyay D, Sreedhar B, et al. Synthesis and characterization of erosslinked polyurethane dispersions based on hydroxylated polyesters [J].J Appl Polym Sci, 2006,99:368~380.
  • 3Levchik S, Weil E D. Thermal decomposition, combustion and fire-retardancy ofpolyurethanes-a review of the recent literature[J]. Polym Int, 2004,53:1585-1610.
  • 4Savita K, Mishra A K, Dipak K, et al. Synthesis and characterization of hyperbranched polyesters and polyurethane coatings [J]. J Polym Sci, part A:Polym Chem, 2007, 45:2673-2688.
  • 5陈建福,李晓,张卫英,蔡锦香.二羟甲基丙酸对聚酯型水性聚氨酯性能的影响[J].石油化工,2008,37(10):1049-1053. 被引量：26
  • 6Rahman M M, Kim H D. Characterization of waterborne polyurethane adhesives containing different soft segments [J]. J Adhesion Sci Technol,2007,21:81-96.
  • 7Coutinho F M B, Delpech M C. Some properties of films cast from polyurethane aquesous dispersions of polyether-based anionomer extended with hydrazine [J]. Polym Test, 1996,15:103-113.

二级参考文献10

  • 1谭晓玲,果云,潘肇琦,董亚明,张波.软段对水性聚氨酯结构与性能的影响[J].功能高分子学报,2004,17(2):235-240. 被引量：38
  • 2Narayan R, Chattopadhyay D, Sreedhar B, et al. Synthesis and Characterization of Crosslinked Polyurethane Dispersions Based on Hydroxylated Polyesters. J Appl Polym Sci, 2006, 99( 1 ) :368 - 380
  • 3Levchik S, Weil E D. Thermal Decomposition, Combustion and Fire-Retardancy of Polyurethanes A Review of the Recent Literature. Polym Int, 2004,53(11):1585 - 1610
  • 4Kumari S, Mishra A K, Dipak K, et al. Synthesis and Characterization of Hyperbranched Polyesters and Polyurethane Coatings. J Polym Sci, Polym Chem, 2007, 45(13) : 2673 -2688
  • 5Rahman M M, Kim H D. Characterization of Waterborne Polyurethane Adhesives Containing Different Soft Segments. J Adhesion Sci Technol,2007,21 ( 1 ) :81 - 96
  • 6Bao Lihong, Lan Yunjun, Zhang Shufen. Synthesis and Properties of Waterborne Polyurethane Dispersions with Ions in the Soft Segments. J Polym Res,2006,13 (6) :507 - 514
  • 7Yen M S, Kuo S C. PCL-PEG-PCL Triblock Ester-Ether Copolydiol-Based Waterbome Polyurethane. ii. Effect of NCO/OH Mole Ratio and DMPA Content on the Physical Properties. J Appl Polym Sci, 1998,67(7) : 1301 - 1344
  • 8Coutinho F M B, Delpech M C. Some Properties of Films Cast from Polyurethane Aquesous Dispersions of Polyether-Based Anionomer Extended with Hydrazine. Polym Test, 1996,15 ( 2 ) : 103 - 113
  • 9张庆思,朱晓丽,李天铎,刘磊力,张萌,于一涛.反应型聚硅氧烷改性聚氨酯水分散体的合成及性能[J].石油化工,2007,36(8):839-845. 被引量：12
  • 10陈延娜,李树材,陈维涛.水性聚氨酯的合成与性能研究(I) 聚氨酯组成对其性能的影响[J].中国皮革,2003,32(3):30-32. 被引量：17

共引文献25

同被引文献27

  • 1王翠,吴佑实,吴莉莉.MDI型水性聚氨酯乳液的合成及性能研究[J].涂料工业,2009,39(2):4-8. 被引量：15
  • 2侯薇,陈龙,王安之,兰延勋,吕满庚.水性聚氨酯涂料的改性方法[J].聚氨酯工业,2006,21(5):13-16. 被引量：7
  • 3于良民,王秀娟.水性聚氨酯的改性及水性聚氨酯涂料[J].热固性树脂,2007,22(4):44-46. 被引量：5
  • 4熊军,孙芳,杜洪光.丙酮-二正丁胺滴定法测定聚氨酯中的异氰酸酯基[J].分析试验室,2007,26(8):73-76. 被引量：140
  • 5MOHAMMAD ALAVI Nikje Mir, TEHRANI Zahra Mazathen. Synthesis and characterization of waterborne polyurethane-chitosan nanocomposites[J]. Polymer-plastics Technology and Engineering, 2010,49 (8) : 812-817.
  • 6KONG Xia, LI Shao Mao, QU Jin Qing, et al. Self-emulsifying hydroxy acrylic polymer dispersions for two component waterborne polyurethane coatings [J]. Journal of Macromolecular Science Part A:Pure and Applied Chemistry,2010,47 (4): 368-374.
  • 7ZHOU Xiao San, PAN Zhao Qi, GAO Yun. A facile synthesis of waterborne polyurethane/silica/CdTe-QDs nanocomposites with excellent mechanical, thermal and optical properties [J]. Optoelectronics and Advanced Materials-rapid Communications, 2011,5 ( 3/4 ) : 281-286.
  • 8LAI Xiao Juan, SHEN Yi Ding, WANG Lei, et al. Preparation and performance of waterborne polyurethane/nanosilica hybrid materials [J]. Polymer-Plastics Technology and Engineering, 2011,50(7): 740-747.
  • 9WANG Lei, SHEN Yi Ding, LAI Xiao Juan, et al. Synthesis and properties of crosslinked waterborne polyurethane[J]. Journal of Polymer Research, 2011,18 (3) : 469-476.
  • 10孙成东 张松 李庆安.高估含量水性聚氨酯的合成及其成膜性能的研究.中国胶黏剂,2008,16(8):11-14.

引证文献4

二级引证文献16

胶体与聚合物
2010年 第2期

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