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阴离子表面活性剂形成微乳液的相行为和增溶能力

Studies on the Phase Behavior and Solubilization of Microemulsion Formed by Anion Surfactants
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摘要 在40℃下,用ε-β"鱼状"相图法研究了阴离子表面活性剂十二烷基磺酸钠(十二烷基硫酸钠、十二烷基苯磺酸钠)/烷烃/脂肪醇/盐水微乳液体系的相行为和增溶能力,测定了亲水-亲油平衡界面膜的组成.结果表明,阴离子表面活性剂亲油基体积越大、油相碳链越短、醇的碳链越长、NaCl的浓度越高,微乳液的增溶能力越强. The phase behavior and solubilization of the microemulsion formed by sodium dodecyl sulfonate(sodium dodecyl sulfate,sodium dodecyl benzene sulfonate)/alcohol/ alkane/brine have been studied with ε-β-fishlike phase diagram at 40 ℃.The composition of the hydrophile-lipophile balanced interfacial layer is determined.The solubilization of the microemulsion system has been discussed based on the ε-β-fishlike phase diagram.The smaller the oil molecule,the longer the alcohol chain length,and the higher the NaCl concentration in water,the stronger the solubilization of the microemulsion system.
作者 秦承宽
出处 《滨州学院学报》 2010年第3期69-73,共5页 Journal of Binzhou University
基金 滨州学院青年人才创新工程科研基金项目(BZXYQNLG200822)
关键词 阴离子表面活性剂 微乳液 ε-β“鱼状”相图 相行为 增溶能力 anion surfactant microemulsion ε-β-fishlike phase diagramhase behavior solubilization
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  • 1Dayalan E,Qurubuddin S,Texter J.Diffusion coefficients of di-/tri-isopropyl naphthalene sulfonate micelles-electrochemical and light scattering measurements[J].J Colloid Interface Sci,1993,158:249-251.
  • 2Bauduin P,Touraud D,Kunz W,et al.The influence of structure and composition of a reverse SDS microemulsion on enzymatic activities and electrical conductivities[J].J Colloid Interface Sci,2005,292:244-254.
  • 3Zhang H W,Dubin P L.Analysis of polydispersity of mixed micelles of TX-100/SDS and C12E8/SDS by capillary electrophoresis[J].J Colloid Interface Sci,1997,186:264-270.
  • 4James-Smith M A,Alford K,Shah D O.Effect of long-chain alcohols on SDS partitioning to the oil/water interface of emulsions and on droplet size[J].J Colloid Interface Sci,2007,315:307-312.
  • 5Chai J L,Li G Z,Zhang G Y,et al.Studies on the phase behavior of the system APG/alcohol/alkane/H2O with fishlike diagrams[J].Colloids Surf A,2003,231:173-180.
  • 6Qin C K,Chai J L,Chen J F,et al.Studies on the phase behavior and solubilization of the microemulsion formed by surfactant-like ionic liquids with ε-β-fish-like phase diagram[J].Colloid Polym Sci,2008,286:579-586.
  • 7Chai J L,Zhao J R,Gao Y H,et al.Studies on the phase behavior of the microemulsions formed by sodium dodecyl sulfonate,sodium dodecyl sulfate and sodium dodecyl benzene sulfonate with a novel fishlike phase diagram[J].Colloid Surf A,2007,302:31-35.
  • 8Penders M H G M,Strey R.Phase behavior of the quaternary system H2O/n-octane/C8E5/n-Octanol:role of the alcohol in microemulsions[J].J Phys Chem,1995,99(25):10313-10318.

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